(a) Interpretation: All constitutional isomers formed by the monochlorination of given alkane is to be drawn. Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C − H sigma bond of the alkane.

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Answer 1

Question

Chapter 15, Problem 15.4P

Interpretation Introduction

(a)

Interpretation:

All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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6. Match each of the lettered items in the column on the left with the most appropriate numbered item(s) in the column on the right. Some of the numbered items may be used more than once and some not at all. a. Z = 37 1. b. Mn 2. C. Pr element in period 5 and group 14 element in period 5 and group 15 d. S e. [Rn] 7s¹ f. d block metal 3. highest metallic character of all the elements 4. paramagnetic with 5 unpaired electrons 5. 4f36s2 6. isoelectronic with Ca²+ cation 7. an alkaline metal 8. an f-block element

Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.

Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1

Answer 2

Question

Chapter 15, Problem 15.4P

Interpretation Introduction

(a)

Interpretation:

All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 3

Question

Chapter 15, Problem 15.4P

Interpretation Introduction

(a)

Interpretation:

All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 4

Question

Chapter 15, Problem 15.4P

Interpretation Introduction

(a)

Interpretation:

All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 5

Chapter 15, Problem 15.4P

Interpretation Introduction

(a)

Interpretation:

All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 6

Chapter 15, Problem 15.4P

Interpretation Introduction

(a)

Interpretation:

All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Answer 7

Chapter 15, Problem 15.4P

Interpretation Introduction

(a)

Interpretation:

All constitutional isomers formed by the monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from the C−H sigma bond of the alkane.

Answer 8

Interpretation Introduction

(b)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 9

Interpretation Introduction

(b)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 10

Interpretation Introduction

(c)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 11

Interpretation Introduction

(c)

Interpretation:

All constitutional isomers formed by monochlorination of given alkane is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Draw the product formed when a chlorine atom (Cl)...Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Calculate m0 for the two propagation steps in the...Ch. 15 - Prob. 15.8P Ch. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.10P

Solution Summary: The author explains that all constitutional isomers formed by monochlorination of given alkane are to be drawn.

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Chapter 15 Solutions