Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 15, Problem 15.36P
Interpretation Introduction
(a)
Interpretation: All constitutional isomers formed by monochlorination of given
Concept introduction: Monochlorination is a type of radical substitution reaction. In this reaction,
Interpretation Introduction
(b)
Interpretation: All constitutional isomers formed by the monochlorination of given alkane with
Concept introduction: Monochlorination is a type of radical substitution reaction. In this reaction, alkyl halides are formed by the replacement of hydrogen by
Interpretation Introduction
(c)
Interpretation: All constitutional isomers formed by monochlorination of given alkane with
Concept introduction: Monochlorination is a type of radical substitution reaction. In this reaction, alkyl halide is formed by the replacement of hydrogen by
Interpretation Introduction
(d)
Interpretation: All constitutional isomers formed by monochlorination of given alkane with
Concept introduction: Monochlorination is a type of radical substitution reaction. In this reaction, alkyl halide is formed by the replacement of hydrogen by
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Name each of the following cyclic alkanes, and indicate the formula of the compound.
CHCH3
а.
CH3
CH3
|
CCH3
b.
CH3
CH3
с. СHз СH-CH-CH3
CH3
Give the structure of an alkane that fi ts each description. a. an alkane that contains only 1 ° and 4 ° carbons b. a cycloalkane that contains only 2 ° carbons c. an alkane of molecular formula C 6H 14 that contains a 4 ° carbon d. a cycloalkane that contains 2 ° and 3 ° carbons
Complete and balance each hydrocarbon combustion reaction.
a. CH;CH;CH,CH3 + O2
b. CH2=CHCH, + 02
c. CH=CCH,CH3 + O2
Chapter 15 Solutions
Organic Chemistry-Package(Custom)
Ch. 15 - Prob. 15.1PCh. 15 - Prob. 15.2PCh. 15 - Draw the product formed when a chlorine atom (Cl)...Ch. 15 - Prob. 15.4PCh. 15 - Prob. 15.5PCh. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Calculate m0 for the two propagation steps in the...Ch. 15 - Prob. 15.8PCh. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.10P
Ch. 15 - Prob. 15.11PCh. 15 - Synthesize each compound from (CH3)3CH. a....Ch. 15 - Prob. 15.13PCh. 15 - Prob. 15.14PCh. 15 - Prob. 15.15PCh. 15 - Prob. 15.16PCh. 15 - Prob. 15.17PCh. 15 - Prob. 15.18PCh. 15 - Draw all constitutional isomers formed when each...Ch. 15 - Draw the structure of the four allylic halides...Ch. 15 - Which compounds can be prepared in good yield by...Ch. 15 - Which CH bond is most readily cleaved in linolenic...Ch. 15 - Prob. 15.23PCh. 15 - Draw the products formed when each alkene is...Ch. 15 - Problem 15.24 When adds to under radical...Ch. 15 - Prob. 15.26PCh. 15 - Draw an energy diagram for the two propagation...Ch. 15 - Prob. 15.28PCh. 15 - Problem 15.27 Draw the steps of the mechanism that...Ch. 15 - Prob. 15.30PCh. 15 - Prob. 15.31PCh. 15 - Prob. 15.32PCh. 15 - Prob. 15.33PCh. 15 - Why is a benzylic CH bond labeled in red unusually...Ch. 15 - Prob. 15.35PCh. 15 - Prob. 15.36PCh. 15 - Prob. 15.37PCh. 15 - Prob. 15.38PCh. 15 - What alkane is needed to make each alkyl halide by...Ch. 15 - Which alkyl halides can be prepared in good yield...Ch. 15 - Prob. 15.41PCh. 15 - 15.40 Explain why radical bromination of p-xylene...Ch. 15 - a. What product(s) (excluding stereoisomers) are...Ch. 15 - Prob. 15.44PCh. 15 - Prob. 15.45PCh. 15 - Prob. 15.46PCh. 15 - 15.44 Draw all constitutional isomers formed when...Ch. 15 - Draw the organic products formed in each reaction....Ch. 15 - Prob. 15.49PCh. 15 - 15.47 Treatment of a hydrocarbon A (molecular...Ch. 15 - Prob. 15.51PCh. 15 - Prob. 15.52PCh. 15 - Prob. 15.53PCh. 15 - Prob. 15.54PCh. 15 - 15.53 Consider the following bromination: .
a....Ch. 15 - 15.54 Draw a stepwise mechanism for the following...Ch. 15 - Prob. 15.57PCh. 15 - An alternative mechanism for the propagation steps...Ch. 15 - Prob. 15.59PCh. 15 - Prob. 15.60PCh. 15 - Devise a synthesis of each compound from...Ch. 15 - Devise a synthesis of each target compound from...Ch. 15 - Devisea synthesis of each target compound from the...Ch. 15 - Devise a synthesis of each compound using CH3CH3...Ch. 15 - Prob. 15.65PCh. 15 - 15.63 As described in Section 9.16, the...Ch. 15 - 15.64 Ethers are oxidized with to form...Ch. 15 - Prob. 15.68PCh. 15 - Prob. 15.69PCh. 15 - 15.67 In cells, vitamin C exists largely as its...Ch. 15 - What monomer is needed to form each...Ch. 15 - Prob. 15.72PCh. 15 - Prob. 15.73PCh. 15 - 15.71 Draw a stepwise mechanism for the following...Ch. 15 - 15.72 As we will learn in Chapter 30, styrene...Ch. 15 - Prob. 15.76PCh. 15 - 15.74 A and B, isomers of molecular formula , are...Ch. 15 - Prob. 15.78PCh. 15 - Radical chlorination of CH3CH3 forms two minor...Ch. 15 - 15.76 Draw a stepwise mechanism for the...Ch. 15 - Prob. 15.81PCh. 15 - Prob. 15.82PCh. 15 - Prob. 15.83P
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- Name each alkyne. CH,-C=C-CH, CH3 b. CH;-C=C-C-CH,-CH, CH3 c. CH=C-CH-CH2-CH2-CH, CH-CH, ČH,arrow_forward8. Name each alkyne. A. CH3CH2CH2C=CH B. CH3CH2CH2C=CCH3arrow_forwardClassify the following alcohol as primary, secondary, or tertiary a. . CH3—СH>—CH—ОН b. CH3 . CH;—СH,— С-ОН CH3 С. CH3 CH3 CH3— СCH—СH— СН—СН; ОН d. HOarrow_forward
- Which reagent is needed to change an alkyne to an alkane? * Н:0+, Hg (COОH)2 N2, Pt Ог, Pd Н, Pt What reaction takes place when an alcohol is produced during the net addition of water across the double bond of an alkene? * Dehydrogenation Hydrogenation Dehydration Hydrationarrow_forward8. What is the IUPAC name of CHCH, CH, CH3-CH-O-CH, CH; Da. 1-ethoxy-1-methylbutane Ob. 2-ethoxypentane O c. 1-methoxyhexane Od. 2-ethoxy-2-n-propylethanearrow_forwardList all the possible products for each alkane substitution reac- tion. (Assume monosubstitution.) a. CH;CH, + Br b. CH;CH,CH, + Cl c. CH,Cl, + Br2 d. CH,-CH-CH, +Clz CH,arrow_forward
- c. CH2-CH2-CH2-CH-CH3 b. C CH3 CH3 d. CH3-CH2-CH-CH,-CH--CH3 CH3 111s C. CH3 12.36 Give the IUPAC name for each of the follov ing d. alkanes. a. CH3-CH,--CH-CH2-CH,-CH3 ČH3 12.39 b. CH3--CH2-CH2-CH-CH3 ČH3 CH c. CH-CH2-CH-CH3 ČH3 CH3 d. CH3-CH-CH2-CH-CH3 CH3 CH3 14.4 12.37 Give the IUPAC name for each of the followi ng alkanes. a. CH3-CH-CH2-CH-CH-CH3 CH3 CH3 CH3 CH3 b. CH3--C-CH,-CH-CH3 CH3 CH3 12 CH3 c. CH3-CH2-C-CH2-CH3 CH2 CH3 CH3 d. CH3-CH2-C-CH2-CH2 CH3 CH2 1. CH3 12.38 Give the IUPAC name for each of the follo ng alkanes. a. CH3-CH2-CH-CH-CH-CH-C CH3 CH2 CH3 CH3arrow_forwardNAME AND CLASSIFY MOLECULES ACCORDING TO THEIR FUNCTIONAL GROUP(S)arrow_forwardIdentify the alkene from the following four molecules. HC. CH HC. CHa CHs CH CH3 2.arrow_forward
- Polyvinyl acetate (PVA), a component of adhesives like wood glue or school glue, has the formula H₂C 1480 Hn H PVA forms by addition polymerization. Draw the monomer. Include all H atoms.arrow_forwardName the three alkenes using systematic names. The name of compound A is: The name of compound B is:arrow_forward25. What is the IUPAC name for H-C =C-CH,CHCH; Br a. 4-bromo-1-pentyne b. 2-bromo-1-pentyne c. 2-bromo-4-pentyne d. 2-bromo-2-pentynearrow_forward
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