Chemistry: Matter and Change
1st Edition
ISBN: 9780078746376
Author: Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher: Glencoe/McGraw-Hill School Pub Co
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Question
Chapter 15, Problem 101A
Interpretation Introduction
Interpretation:
ΔGosystem is to be calculated.
Concept introduction:
Free energy change, ΔGsystem is the difference between the system’s change in enthalpy ( ΔHsystem ) and the product of the kelvin temperature and the change in entropy ( TΔSsystem ). That is,
ΔGsystem = ΔHsystem-TΔSsystem
Expert Solution & Answer
Answer to Problem 101A
Standard free energy change, ΔSosystem for the change from H2O(l)→H2O(g) is 0.11kJ/K
Explanation of Solution
When a reaction or process occurs under standard conditions (298 K and 1 atm), the standard free energy change can be expressed as follows.
ΔGosystem = ΔHosystem-TΔSosystem
Given information,
ΔGosystem=8.55kJΔHosystem=44.01kJT=298K
ΔGosystem = ΔHosystem-TΔSosystem8.557kJ=44.01kJ-298KΔSosystem298KΔSosystem=44.01kJ-8.557kJΔSosystem=35.456kJ298KΔSosystem=0.11kJ/K
Conclusion
If the sign of the free energy change( ΔGosystem ) is negative, the reaction is spontaneous and if the sign of the free energy change ( ΔGosystem ) is positive, the reaction is nonspontaneous.
Chapter 15 Solutions
Chemistry: Matter and Change
Ch. 15.1 - Prob. 1PPCh. 15.1 - Prob. 2PPCh. 15.1 - Prob. 3PPCh. 15.1 - Prob. 4PPCh. 15.1 - Prob. 5PPCh. 15.1 - Prob. 6PPCh. 15.1 - Prob. 7SSCCh. 15.1 - Prob. 8SSCCh. 15.1 - Prob. 9SSCCh. 15.1 - Prob. 10SSC
Ch. 15.1 - Prob. 11SSCCh. 15.2 - Prob. 12PPCh. 15.2 - Prob. 13PPCh. 15.2 - Prob. 14PPCh. 15.2 - Prob. 15PPCh. 15.2 - Prob. 16SSCCh. 15.2 - Prob. 17SSCCh. 15.2 - Prob. 18SSCCh. 15.2 - Prob. 19SSCCh. 15.2 - Prob. 20SSCCh. 15.2 - Prob. 21SSCCh. 15.2 - Prob. 22SSCCh. 15.3 - Prob. 23PPCh. 15.3 - Prob. 24PPCh. 15.3 - Prob. 25PPCh. 15.3 - Prob. 26SSCCh. 15.3 - Prob. 27SSCCh. 15.3 - Prob. 28SSCCh. 15.3 - Prob. 29SSCCh. 15.3 - Prob. 30SSCCh. 15.3 - Prob. 31SSCCh. 15.4 - Prob. 32PPCh. 15.4 - Prob. 33PPCh. 15.4 - Prob. 34PPCh. 15.4 - Prob. 35PPCh. 15.4 - Prob. 36PPCh. 15.4 - Prob. 37PPCh. 15.4 - Prob. 38SSCCh. 15.4 - Prob. 39SSCCh. 15.4 - Prob. 40SSCCh. 15.4 - Prob. 41SSCCh. 15.4 - Prob. 42SSCCh. 15.4 - Prob. 43SSCCh. 15.5 - Prob. 44PPCh. 15.5 - Prob. 45PPCh. 15.5 - Prob. 46PPCh. 15.5 - Prob. 47PPCh. 15.5 - Prob. 48SSCCh. 15.5 - Prob. 49SSCCh. 15.5 - Prob. 50SSCCh. 15.5 - Prob. 51SSCCh. 15.5 - Prob. 52SSCCh. 15 - Prob. 53ACh. 15 - Prob. 54ACh. 15 - Prob. 55ACh. 15 - Prob. 56ACh. 15 - Prob. 57ACh. 15 - Prob. 58ACh. 15 - Prob. 59ACh. 15 - Prob. 60ACh. 15 - Prob. 61ACh. 15 - Prob. 62ACh. 15 - Prob. 63ACh. 15 - Prob. 64ACh. 15 - Prob. 65ACh. 15 - Prob. 66ACh. 15 - Metallurgy A 25.0-g bolt made of an alloy...Ch. 15 - Prob. 68ACh. 15 - Prob. 69ACh. 15 - Prob. 70ACh. 15 - Prob. 71ACh. 15 - Prob. 72ACh. 15 - Prob. 73ACh. 15 - How many joules of heat are lost by 3580 kg of...Ch. 15 - Swimming Pool A swimming pool measuring 20.0m12.5m...Ch. 15 - How much heat is absorbed by a 44.7-g piece of...Ch. 15 - Prob. 77ACh. 15 - Alloys When a 58.8-g piece of hot alloy is placed...Ch. 15 - Prob. 79ACh. 15 - Prob. 80ACh. 15 - Prob. 81ACh. 15 - Prob. 82ACh. 15 - sUse information from Figure 15.24 to calculate...Ch. 15 - Agriculture Water is sprayed on oranges during...Ch. 15 - Grilling What mass of propane (C3H8) must be...Ch. 15 - Heating with Coal How much heat is liberated...Ch. 15 - How much heat is evolved when 1255 g of water...Ch. 15 - A sample of ammonia (Hsolid=5.66kJ/mol)...Ch. 15 - Prob. 89ACh. 15 - Prob. 90ACh. 15 - Prob. 91ACh. 15 - Prob. 92ACh. 15 - Prob. 93ACh. 15 - Prob. 94ACh. 15 - Prob. 95ACh. 15 - Prob. 96ACh. 15 - Prob. 97ACh. 15 - Prob. 98ACh. 15 - Prob. 99ACh. 15 - Prob. 100ACh. 15 - Prob. 101ACh. 15 - Prob. 102ACh. 15 - Prob. 103ACh. 15 - Heat was added consistently to a sample of water...Ch. 15 - Bicycling Describe the energy conversions that...Ch. 15 - Hiking Imagine that on a cold day you are planning...Ch. 15 - Differentiate between the enthalpy of formation of...Ch. 15 - Analyze both of the images in Figure 15.27 in...Ch. 15 - Apply Phosphorus trichloride is a starting...Ch. 15 - Calculate Suppose that two pieces of iron, one...Ch. 15 - Prob. 111ACh. 15 - sample of natural gas is analyzed and found to...Ch. 15 - Prob. 113ACh. 15 - Prob. 114ACh. 15 - Prob. 115ACh. 15 - Prob. 116ACh. 15 - Prob. 117ACh. 15 - Prob. 118ACh. 15 - Prob. 119ACh. 15 - Prob. 120ACh. 15 - Prob. 121ACh. 15 - Prob. 122ACh. 15 - Prob. 123ACh. 15 - Prob. 124ACh. 15 - Prob. 125ACh. 15 - Prob. 126ACh. 15 - Prob. 127ACh. 15 - Prob. 1STPCh. 15 - Prob. 2STPCh. 15 - Prob. 3STPCh. 15 - Prob. 4STPCh. 15 - Prob. 5STPCh. 15 - Prob. 6STPCh. 15 - Prob. 7STPCh. 15 - Prob. 8STPCh. 15 - Prob. 9STPCh. 15 - Prob. 10STPCh. 15 - Prob. 11STPCh. 15 - Prob. 12STPCh. 15 - Prob. 13STPCh. 15 - Prob. 14STPCh. 15 - Prob. 15STPCh. 15 - Prob. 16STPCh. 15 - Prob. 17STPCh. 15 - Prob. 18STP
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