General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 14.6, Problem 14.12P
Interpretation Introduction

Interpretation:

The oxidation products formed during the metabolism of ethylene glycol should be drawn.

Concept Introduction:

Primary alcohols are first oxidized to aldehydes and then to carboxylic acid by replacing C-H bonds by C-O bonds. Secondary alcohols are oxidized to ketones and tertiary alcohols do not undergo oxidation as they have no H atoms on the C with OH group.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

Chapter 14 Solutions

General, Organic, & Biological Chemistry

Ch. 14.5 - Prob. 14.11PCh. 14.6 - Prob. 14.12PCh. 14.6 - Prob. 14.13PCh. 14.7 - Prob. 14.14PCh. 14.7 - Prob. 14.15PCh. 14.7 - Prob. 14.16PCh. 14.7 - Prob. 14.17PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.9 - Prob. 14.21PCh. 14.9 - Prob. 14.22PCh. 14.9 - Prob. 14.23PCh. 14.9 - Prob. 14.24PCh. 14.9 - Prob. 14.25PCh. 14.10 - Prob. 14.26PCh. 14.10 - Prob. 14.27PCh. 14.10 - Prob. 14.28PCh. 14 - Prob. 14.29PCh. 14 - Prob. 14.30PCh. 14 - Prob. 14.31PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 14.33PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Prob. 14.37PCh. 14 - Prob. 14.38PCh. 14 - Prob. 14.39PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 14.41PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 14.43PCh. 14 - Prob. 14.44PCh. 14 - Prob. 14.45PCh. 14 - Prob. 14.46PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 14.48PCh. 14 - Prob. 14.49PCh. 14 - Prob. 14.50PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 14.57PCh. 14 - Prob. 14.58PCh. 14 - Prob. 14.59PCh. 14 - Prob. 14.60PCh. 14 - Prob. 14.61PCh. 14 - Prob. 14.62PCh. 14 - Prob. 14.63PCh. 14 - Prob. 14.64PCh. 14 - Prob. 14.65PCh. 14 - Prob. 14.66PCh. 14 - Prob. 14.67PCh. 14 - Prob. 14.68PCh. 14 - Prob. 14.69PCh. 14 - Prob. 14.70PCh. 14 - Prob. 14.71PCh. 14 - Prob. 14.72PCh. 14 - Prob. 14.73PCh. 14 - Prob. 14.74PCh. 14 - Prob. 14.75PCh. 14 - Prob. 14.76PCh. 14 - Prob. 14.77PCh. 14 - Prob. 14.78PCh. 14 - Prob. 14.79PCh. 14 - Prob. 14.80PCh. 14 - Prob. 14.81PCh. 14 - Prob. 14.82PCh. 14 - Prob. 14.83PCh. 14 - Prob. 14.84PCh. 14 - Prob. 14.85PCh. 14 - Prob. 14.86PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 14.88PCh. 14 - Prob. 14.89PCh. 14 - Prob. 14.90PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 14.92PCh. 14 - Prob. 14.93PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 14.95PCh. 14 - Prob. 14.96PCh. 14 - Prob. 14.97PCh. 14 - Prob. 14.98PCh. 14 - Prob. 14.99PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 14.101CPCh. 14 - Dehydration of alcohol C forms two products of...
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