(a) Interpretation: The structural formula of 3-chloro-2-methylhexane should be determined. Concept Introduction: Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula C n H 2 n + 2 . The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide . Rules of drawing structures of organic compounds are: First identify the base name, and then draw the straight chain of carbon atoms according to the base name. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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Answer 1

Question

Chapter 14.9, Problem 14.24P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 3-chloro-2-methylhexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 4-ethyl-5-iodo-2,2-dimethyloctane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 1,1,3-tribromocyclohexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is CnH2n.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of propyl chloride should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

Answer 2

Question

Chapter 14.9, Problem 14.24P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 3-chloro-2-methylhexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 4-ethyl-5-iodo-2,2-dimethyloctane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 1,1,3-tribromocyclohexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is CnH2n.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of propyl chloride should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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Answer 3

Question

Chapter 14.9, Problem 14.24P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 3-chloro-2-methylhexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 4-ethyl-5-iodo-2,2-dimethyloctane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 1,1,3-tribromocyclohexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is CnH2n.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of propyl chloride should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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Answer 4

Question

Chapter 14.9, Problem 14.24P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 3-chloro-2-methylhexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 4-ethyl-5-iodo-2,2-dimethyloctane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 1,1,3-tribromocyclohexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is CnH2n.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of propyl chloride should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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Answer 5

Chapter 14.9, Problem 14.24P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 3-chloro-2-methylhexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 4-ethyl-5-iodo-2,2-dimethyloctane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 1,1,3-tribromocyclohexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is CnH2n.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of propyl chloride should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 6

Chapter 14.9, Problem 14.24P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 3-chloro-2-methylhexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 7

Chapter 14.9, Problem 14.24P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 3-chloro-2-methylhexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structural formula of 4-ethyl-5-iodo-2,2-dimethyloctane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structural formula of 4-ethyl-5-iodo-2,2-dimethyloctane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structural formula of 1,1,3-tribromocyclohexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is CnH2n.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structural formula of 1,1,3-tribromocyclohexane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is CnH2n.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structural formula of propyl chloride should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structural formula of propyl chloride should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of organic compounds are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.2P Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Prob. 14.5P Ch. 14.3 - Prob. 14.6P Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.9P Ch. 14.5 - Prob. 14.10P

Solution Summary: The author explains how the structural formula of 3-chloro-2-methylhexane should be determined.

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