(a) Interpretation: Thiols should be identified after reduction of C H 3 S − S C H 2 C H 2 C H 3 . Concept Introduction: Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon. Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

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Answer 1

Question

Chapter 14, Problem 14.83P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे

Answer 2

Question

Chapter 14, Problem 14.83P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

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Answer 3

Question

Chapter 14, Problem 14.83P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 14.83P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

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Answer 5

Chapter 14, Problem 14.83P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

Answer 6

Chapter 14, Problem 14.83P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Answer 7

Chapter 14, Problem 14.83P

Interpretation Introduction

(a)

Interpretation:

Thiols should be identified after reduction of CH3S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agentwill form thiolsand the reaction is known as a reduction reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Thiols should be identified after reduction of CH2=CHCH2S−SCH2CH2CH3.

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of disulfides with reducing agent will form thiols and the reaction is known as a reduction reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.2P Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Prob. 14.5P Ch. 14.3 - Prob. 14.6P Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.9P Ch. 14.5 - Prob. 14.10P

Solution Summary: The author explains that thiols are considered as sulfur analogs of alcohols since S is placed directly below to the oxygen in the periodic table and disulfides undergo reduction reactions.

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Chapter 14 Solutions