General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 14, Problem 14.46P
Interpretation Introduction

(a)

Interpretation:

An acceptable name for the following ether should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.46P , additional homework tip  1

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

An acceptable name for the following ether should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.46P , additional homework tip  2

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(c)

Interpretation:

An acceptable name for the following ether should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.46P , additional homework tip  3

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

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Chapter 14 Solutions

General, Organic, & Biological Chemistry

Ch. 14.5 - Prob. 14.11PCh. 14.6 - Prob. 14.12PCh. 14.6 - Prob. 14.13PCh. 14.7 - Prob. 14.14PCh. 14.7 - Prob. 14.15PCh. 14.7 - Prob. 14.16PCh. 14.7 - Prob. 14.17PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.9 - Prob. 14.21PCh. 14.9 - Prob. 14.22PCh. 14.9 - Prob. 14.23PCh. 14.9 - Prob. 14.24PCh. 14.9 - Prob. 14.25PCh. 14.10 - Prob. 14.26PCh. 14.10 - Prob. 14.27PCh. 14.10 - Prob. 14.28PCh. 14 - Prob. 14.29PCh. 14 - Prob. 14.30PCh. 14 - Prob. 14.31PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 14.33PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Prob. 14.37PCh. 14 - Prob. 14.38PCh. 14 - Prob. 14.39PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 14.41PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 14.43PCh. 14 - Prob. 14.44PCh. 14 - Prob. 14.45PCh. 14 - Prob. 14.46PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 14.48PCh. 14 - Prob. 14.49PCh. 14 - Prob. 14.50PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 14.57PCh. 14 - Prob. 14.58PCh. 14 - Prob. 14.59PCh. 14 - Prob. 14.60PCh. 14 - Prob. 14.61PCh. 14 - Prob. 14.62PCh. 14 - Prob. 14.63PCh. 14 - Prob. 14.64PCh. 14 - Prob. 14.65PCh. 14 - Prob. 14.66PCh. 14 - Prob. 14.67PCh. 14 - Prob. 14.68PCh. 14 - Prob. 14.69PCh. 14 - Prob. 14.70PCh. 14 - Prob. 14.71PCh. 14 - Prob. 14.72PCh. 14 - Prob. 14.73PCh. 14 - Prob. 14.74PCh. 14 - Prob. 14.75PCh. 14 - Prob. 14.76PCh. 14 - Prob. 14.77PCh. 14 - Prob. 14.78PCh. 14 - Prob. 14.79PCh. 14 - Prob. 14.80PCh. 14 - Prob. 14.81PCh. 14 - Prob. 14.82PCh. 14 - Prob. 14.83PCh. 14 - Prob. 14.84PCh. 14 - Prob. 14.85PCh. 14 - Prob. 14.86PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 14.88PCh. 14 - Prob. 14.89PCh. 14 - Prob. 14.90PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 14.92PCh. 14 - Prob. 14.93PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 14.95PCh. 14 - Prob. 14.96PCh. 14 - Prob. 14.97PCh. 14 - Prob. 14.98PCh. 14 - Prob. 14.99PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 14.101CPCh. 14 - Dehydration of alcohol C forms two products of...
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