General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 14, Problem 14.41P
Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following compound should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.41P , additional homework tip  1

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Expert Solution
Check Mark

Answer to Problem 14.41P

2-pentanol.

Explanation of Solution

  C5H12O contains five membered main carbon chain. -OH group is connected to the main carbon chain from the 2nd position. There are no other sub groups which connect to the main carbon chain. Hence; IUPAC name for the C5H12O is 2-pentanol.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the following compound should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.41P , additional homework tip  2

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Expert Solution
Check Mark

Answer to Problem 14.41P

3,3-dimethyl-2-hexanol.

Explanation of Solution

( C8H18O ) contains six membered main carbon chain. Methyl groups are connected to the main carbon chain from the 3rd position and OH group is connected to the main carbon chain through 2nd position. Hence; IUPAC name for the C8H18O is 3,3-dimethyl-2-hexanol.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the following compound should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.41P , additional homework tip  3

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Expert Solution
Check Mark

Answer to Problem 14.41P

4-ethyl-6-methylheptanol.

Explanation of Solution

( C10H22O ) contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 6thposition ethyl group is connected to the main carbon chain from 4th position of the main carbon chain and OH group is connected to the main carbon chain through 1st position. Hence; IUPAC name for the C10H22O is 4-ethyl-6-methylheptanol.

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the following compound should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.41P , additional homework tip  4

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Expert Solution
Check Mark

Answer to Problem 14.41P

4-butylcyclohexanol.

Explanation of Solution

( C10H20O ) contains six membered main carbon ring and OH group is directly connected to the cylohexane ring. Butyl group is connected to the cylohexane ring via 1st position. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C10H20O ) is 4-butylcyclohexanol.

Interpretation Introduction

(e)

Interpretation:

The IUPAC name of the following compound should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.41P , additional homework tip  5

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Expert Solution
Check Mark

Answer to Problem 14.41P

2,2-dimethylcyclobutanol.

Explanation of Solution

( C6H12O ) contains four membered main carbon ring and OH group is directly connected to the cylobutane ring. Methyl groups are connected to the cylobutane ring via 2ndposition. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C6H12O ) is 2,2-dimethylcyclobutane.

Interpretation Introduction

(f)

Interpretation:

The IUPAC name of the following compound should be determined:

  General, Organic, & Biological Chemistry, Chapter 14, Problem 14.41P , additional homework tip  6

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Expert Solution
Check Mark

Answer to Problem 14.41P

2,5-diethylcyclopentanol.

Explanation of Solution

( C9H18O ) contains five membered main carbon ring and OH group is directly connected to the cylopentanering. Ethyl groups are connected to the cyclopentane ring through 2nd and 5th positions. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C9H18O ) is 2,5-diethylcyclopentanol.

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Chapter 14 Solutions

General, Organic, & Biological Chemistry

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