
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 14, Problem 14.59P
Interpretation Introduction
Interpretation:
The given compounds need to be matched with the correct boiling point.
Concept Introduction:
Alcohols have high boiling points due to the presence of hydroxyl group in them. The hydroxyl groups result in the formation of hydrogen bonding in alcohol.
As the number of carbon atoms increases in alcohol, the boiling point increases. If the number of carbon atoms is less, the hydroxyl group is more available to form hydrogen bonding with water molecules and the compound will have high boiling point.
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1. Using a Model set Build a model for the following compound
[CH2BrCI].
2. Build another model of the mirror image of your first molecule.
3. Place the two models next to each other and take a picture which shows the
differences between the two models.
4. Determine the absolute stereochemistry R or S for the two models.
5. Write or type a paragraph to Discuss the stereochemical relationship
between the two models of CH2BrCl. You must provide an explanation for
your conclusions also provide a description for the colors used to represent
each atom in the model's images.
What parameters are included in the specific rotation calculation of a pure substance
based on measurement from a polarimeter?
Select one or more:
Density of the sample
Pathlength of the sample container
Enantiomeric excess of the sample
Measured rotation of light
V
Determine whether the following molecule is a hemiacetal, acetal, or neither and select the appropriate box below.
Also, highlight the hemiacetal or acetal carbon if there is one.
Explanation
O
CH O
Ohemiacetal Oacetal Oneither
Check
A
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000
Ar
Chapter 14 Solutions
General, Organic, & Biological Chemistry
Ch. 14.1 - Prob. 14.1PCh. 14.2 - Prob. 14.2PCh. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.4PCh. 14.2 - Prob. 14.5PCh. 14.3 - Prob. 14.6PCh. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.9PCh. 14.5 - Prob. 14.10P
Ch. 14.5 - Prob. 14.11PCh. 14.6 - Prob. 14.12PCh. 14.6 - Prob. 14.13PCh. 14.7 - Prob. 14.14PCh. 14.7 - Prob. 14.15PCh. 14.7 - Prob. 14.16PCh. 14.7 - Prob. 14.17PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.9 - Prob. 14.21PCh. 14.9 - Prob. 14.22PCh. 14.9 - Prob. 14.23PCh. 14.9 - Prob. 14.24PCh. 14.9 - Prob. 14.25PCh. 14.10 - Prob. 14.26PCh. 14.10 - Prob. 14.27PCh. 14.10 - Prob. 14.28PCh. 14 - Prob. 14.29PCh. 14 - Prob. 14.30PCh. 14 - Prob. 14.31PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 14.33PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Prob. 14.37PCh. 14 - Prob. 14.38PCh. 14 - Prob. 14.39PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 14.41PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 14.43PCh. 14 - Prob. 14.44PCh. 14 - Prob. 14.45PCh. 14 - Prob. 14.46PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 14.48PCh. 14 - Prob. 14.49PCh. 14 - Prob. 14.50PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 14.57PCh. 14 - Prob. 14.58PCh. 14 - Prob. 14.59PCh. 14 - Prob. 14.60PCh. 14 - Prob. 14.61PCh. 14 - Prob. 14.62PCh. 14 - Prob. 14.63PCh. 14 - Prob. 14.64PCh. 14 - Prob. 14.65PCh. 14 - Prob. 14.66PCh. 14 - Prob. 14.67PCh. 14 - Prob. 14.68PCh. 14 - Prob. 14.69PCh. 14 - Prob. 14.70PCh. 14 - Prob. 14.71PCh. 14 - Prob. 14.72PCh. 14 - Prob. 14.73PCh. 14 - Prob. 14.74PCh. 14 - Prob. 14.75PCh. 14 - Prob. 14.76PCh. 14 - Prob. 14.77PCh. 14 - Prob. 14.78PCh. 14 - Prob. 14.79PCh. 14 - Prob. 14.80PCh. 14 - Prob. 14.81PCh. 14 - Prob. 14.82PCh. 14 - Prob. 14.83PCh. 14 - Prob. 14.84PCh. 14 - Prob. 14.85PCh. 14 - Prob. 14.86PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 14.88PCh. 14 - Prob. 14.89PCh. 14 - Prob. 14.90PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 14.92PCh. 14 - Prob. 14.93PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 14.95PCh. 14 - Prob. 14.96PCh. 14 - Prob. 14.97PCh. 14 - Prob. 14.98PCh. 14 - Prob. 14.99PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 14.101CPCh. 14 - Dehydration of alcohol C forms two products of...
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