EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Chapter 14, Problem 14.35P

Draw the structure of the six constitutional isomers of molecular formula C 5 H 12 O that contain an ether as functionalgroup.

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13.84. Chlorine atoms react with methane, forming HCI and CH3. The rate constant for the reaction is 6.0 × 107 M¹ s¹ at 298 K. When the experiment was run at three other temperatures, the following data were collected: T (K) k (M-1 s-1) 303 6.5 × 107 308 7.0 × 107 313 7.5 x 107 a. Calculate the values of the activation energy and the frequency factor for the reaction. b. What is the value of the rate constant in the lower stratosphere, where T = 218 K?
My Organic Chemistry textbook says about the formation of cyclic hemiacetals, "Such intramolecular reactions to form five- and six-membered rings are faster than the corresponding intermolecular reactions.  The two reacting functional groups, in this case OH and C=O, are held in close proximity, increasing the probability of reaction."According to the book, the formation of cyclic hemiacetals occurs in acidic conditions. So my question is whether the carbonyl group in this reaction reacts first with the end alcohol on the same molecule or with the ethylene glycol.  And, given the explanation in the book, if it reacts first with ethylene glycol before its own end alcohol, why would it?  I don't need to know the final answer.  I need to know WHY it would not undergo an intermolecular reaction prior to reacting with the ethylene glycol if that is the case.  Please do not use an AI answer.
Don't used hand raiting and don't used Ai solution

Chapter 14 Solutions

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM

Ch. 14.5 - Prob. 14.11PCh. 14.6 - Prob. 14.12PCh. 14.6 - Prob. 14.13PCh. 14.7 - Prob. 14.14PCh. 14.7 - Prob. 14.15PCh. 14.7 - Prob. 14.16PCh. 14.7 - Prob. 14.17PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.9 - Prob. 14.21PCh. 14.9 - Prob. 14.22PCh. 14.9 - Prob. 14.23PCh. 14.9 - Prob. 14.24PCh. 14.9 - Prob. 14.25PCh. 14.10 - Prob. 14.26PCh. 14.10 - Prob. 14.27PCh. 14.10 - Prob. 14.28PCh. 14 - Prob. 14.29PCh. 14 - Prob. 14.30PCh. 14 - Prob. 14.31PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 14.33PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Prob. 14.37PCh. 14 - Prob. 14.38PCh. 14 - Prob. 14.39PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 14.41PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 14.43PCh. 14 - Prob. 14.44PCh. 14 - Prob. 14.45PCh. 14 - Prob. 14.46PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 14.48PCh. 14 - Prob. 14.49PCh. 14 - Prob. 14.50PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 14.57PCh. 14 - Prob. 14.58PCh. 14 - Prob. 14.59PCh. 14 - Prob. 14.60PCh. 14 - Prob. 14.61PCh. 14 - Prob. 14.62PCh. 14 - Prob. 14.63PCh. 14 - Prob. 14.64PCh. 14 - Prob. 14.65PCh. 14 - Prob. 14.66PCh. 14 - Prob. 14.67PCh. 14 - Prob. 14.68PCh. 14 - Prob. 14.69PCh. 14 - Prob. 14.70PCh. 14 - Prob. 14.71PCh. 14 - Prob. 14.72PCh. 14 - Prob. 14.73PCh. 14 - Prob. 14.74PCh. 14 - Prob. 14.75PCh. 14 - Prob. 14.76PCh. 14 - Prob. 14.77PCh. 14 - Prob. 14.78PCh. 14 - Prob. 14.79PCh. 14 - Prob. 14.80PCh. 14 - Prob. 14.81PCh. 14 - Prob. 14.82PCh. 14 - Prob. 14.83PCh. 14 - Prob. 14.84PCh. 14 - Prob. 14.85PCh. 14 - Prob. 14.86PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 14.88PCh. 14 - Prob. 14.89PCh. 14 - Prob. 14.90PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 14.92PCh. 14 - Prob. 14.93PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 14.95PCh. 14 - Prob. 14.96PCh. 14 - Prob. 14.97PCh. 14 - Prob. 14.98PCh. 14 - Prob. 14.99PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 14.101CPCh. 14 - Dehydration of alcohol C forms two products of...
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