(a) Interpretation: The structure of secondary alcohol having molecular formula C 6 H 14 O should be drawn. Concept Introduction: Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond. When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1 ° ) alcohol. When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2 ° ) alcohol. When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3 ° ) alcohol.

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Answer 1

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 14, Problem 14.33P

Interpretation Introduction

(a)

Interpretation:

The structure of secondary alcohol having molecular formula C6H14O should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alcohol.

Interpretation Introduction

(b)

Interpretation:

The structure of ether having molecular formula C6H14O which has a methyl group bonded to oxygen should be drawn.

Concept Introduction:

Ether contains an oxygen atom which is linked with two alkyl groups or two aryl groups or one oxygen atom is linked with two carbon atoms by single bond.

The general structure of ether is:

Where R and R^' is alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure of tertiary alkyl halide having molecular formula C5H11Br should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alkyl halide.

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Answer 2

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 14, Problem 14.33P

Interpretation Introduction

(a)

Interpretation:

The structure of secondary alcohol having molecular formula C6H14O should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alcohol.

Interpretation Introduction

(b)

Interpretation:

The structure of ether having molecular formula C6H14O which has a methyl group bonded to oxygen should be drawn.

Concept Introduction:

Ether contains an oxygen atom which is linked with two alkyl groups or two aryl groups or one oxygen atom is linked with two carbon atoms by single bond.

The general structure of ether is:

Where R and R^' is alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure of tertiary alkyl halide having molecular formula C5H11Br should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alkyl halide.

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Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 14, Problem 14.33P

Interpretation Introduction

(a)

Interpretation:

The structure of secondary alcohol having molecular formula C6H14O should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alcohol.

Interpretation Introduction

(b)

Interpretation:

The structure of ether having molecular formula C6H14O which has a methyl group bonded to oxygen should be drawn.

Concept Introduction:

Ether contains an oxygen atom which is linked with two alkyl groups or two aryl groups or one oxygen atom is linked with two carbon atoms by single bond.

The general structure of ether is:

Where R and R^' is alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure of tertiary alkyl halide having molecular formula C5H11Br should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alkyl halide.

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 14, Problem 14.33P

Interpretation Introduction

(a)

Interpretation:

The structure of secondary alcohol having molecular formula C6H14O should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alcohol.

Interpretation Introduction

(b)

Interpretation:

The structure of ether having molecular formula C6H14O which has a methyl group bonded to oxygen should be drawn.

Concept Introduction:

Ether contains an oxygen atom which is linked with two alkyl groups or two aryl groups or one oxygen atom is linked with two carbon atoms by single bond.

The general structure of ether is:

Where R and R^' is alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure of tertiary alkyl halide having molecular formula C5H11Br should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alkyl halide.

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Answer 5

Chapter 14, Problem 14.33P

Interpretation Introduction

(a)

Interpretation:

The structure of secondary alcohol having molecular formula C6H14O should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alcohol.

Interpretation Introduction

(b)

Interpretation:

The structure of ether having molecular formula C6H14O which has a methyl group bonded to oxygen should be drawn.

Concept Introduction:

Ether contains an oxygen atom which is linked with two alkyl groups or two aryl groups or one oxygen atom is linked with two carbon atoms by single bond.

The general structure of ether is:

Where R and R^' is alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure of tertiary alkyl halide having molecular formula C5H11Br should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alkyl halide.

Answer 6

Chapter 14, Problem 14.33P

Interpretation Introduction

(a)

Interpretation:

The structure of secondary alcohol having molecular formula C6H14O should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alcohol.

Answer 7

Chapter 14, Problem 14.33P

Interpretation Introduction

(a)

Interpretation:

The structure of secondary alcohol having molecular formula C6H14O should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alcohol.

When the hydroxyl group (-OH) is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alcohol.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of ether having molecular formula C6H14O which has a methyl group bonded to oxygen should be drawn.

Concept Introduction:

Ether contains an oxygen atom which is linked with two alkyl groups or two aryl groups or one oxygen atom is linked with two carbon atoms by single bond.

The general structure of ether is:

Where R and R^' is alkyl or aryl groups.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of ether having molecular formula C6H14O which has a methyl group bonded to oxygen should be drawn.

Concept Introduction:

Ether contains an oxygen atom which is linked with two alkyl groups or two aryl groups or one oxygen atom is linked with two carbon atoms by single bond.

The general structure of ether is:

Where R and R^' is alkyl or aryl groups.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of tertiary alkyl halide having molecular formula C5H11Br should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alkyl halide.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of tertiary alkyl halide having molecular formula C5H11Br should be drawn.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Hydrocarbons are classified as saturated hydrocarbon and unsaturated hydrocarbon. Saturated hydrocarbons are those hydrocarbons in which carbon-carbon single bond is present as carbon is linked with four atoms. Unsaturated hydrocarbons are those hydrocarbons in which carbon-carbon multiple bonds are present that is double and triple bond.

The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to one other carbon atom is known as primary ( 1° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to two other carbon atoms is known as secondary ( 2° ) alkyl halide.

When the halogen is present on the carbon atom and that carbon atom is bonded to three other carbon atoms is known as tertiary ( 3° ) alkyl halide.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.2P Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Prob. 14.5P Ch. 14.3 - Prob. 14.6P Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.9P Ch. 14.5 - Prob. 14.10P

Solution Summary: The author explains the structure of secondary alcohol with a methyl group bonded to oxygen.

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