Give the IUAPC name for each alcohol.

Question

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Answer 1

Textbook Question

Chapter 14, Problem 14.42P

Give the IUAPC name for each alcohol.
Chapter 14, Problem 14.42P, Give the IUAPC name for each alcohol. , example 1

Expert Solution

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 1

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

6-methyl-3-heptanol.

Explanation of Solution

C8H18O contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 6^t^h position and OH group is connected to the main carbon chain via 3^r^d position. Hence; IUPAC name for the C8H18O is 6-methyl-3-heptanol.

Expert Solution

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 2

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

2-ethylpentanol.

Explanation of Solution

( C7H16O ) contains five membered main carbon chain. Ethyl group is connected to the main carbon chain from the 2ⁿ^d position and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H16O is 2-ethylpentanol.

Expert Solution

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 3

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3-methylheptanol.

Explanation of Solution

( C7H18O ) contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 3^r^dposition and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H18O is 3-methylheptanol.

Expert Solution

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 4

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1,2,3-propantriol.

Explanation of Solution

( C3H8O3 ) contains three membered main carbon chain. Each carbon connects to a OH group and this C3H8O3 is a triolwhich means more than one OH group. -triol suffix is added to the end of the parent alcohol and numbers are added as a prefix to indicate the positions of the -OH groups. Hence; IUPAC name for the C3H8O3 is1,2,3-propanthriol.

Expert Solution

Interpretation Introduction

(e)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 5

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1-ethyl-2-methylcyclopentanol.

Explanation of Solution

( C8H16O ) contains five membered main carbon ring and OH group is directly connected to the cylopentane ring. Ethyl group is connected to the cylopentane ring via 1^s^t position and methyl group is connected via 2ⁿ^d position. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 1-ethyl-2-methylcyclopentanol.

Expert Solution

Interpretation Introduction

(f)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 6

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3,4-dimethylcyclohexanol.

Explanation of Solution

( C8H16O ) contains six membered main carbon ring and OH group is directly connected to the cylohexane ring. Methyl groups are connected to the cyclohexane ring through 3^r^d and 4^t^h positions. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 3,4-dimethylcyclohexanol.

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Answer 2

Textbook Question

Chapter 14, Problem 14.42P

Give the IUAPC name for each alcohol.
Chapter 14, Problem 14.42P, Give the IUAPC name for each alcohol. , example 1

Expert Solution

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 1

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

6-methyl-3-heptanol.

Explanation of Solution

C8H18O contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 6^t^h position and OH group is connected to the main carbon chain via 3^r^d position. Hence; IUPAC name for the C8H18O is 6-methyl-3-heptanol.

Expert Solution

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 2

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

2-ethylpentanol.

Explanation of Solution

( C7H16O ) contains five membered main carbon chain. Ethyl group is connected to the main carbon chain from the 2ⁿ^d position and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H16O is 2-ethylpentanol.

Expert Solution

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 3

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3-methylheptanol.

Explanation of Solution

( C7H18O ) contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 3^r^dposition and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H18O is 3-methylheptanol.

Expert Solution

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 4

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1,2,3-propantriol.

Explanation of Solution

( C3H8O3 ) contains three membered main carbon chain. Each carbon connects to a OH group and this C3H8O3 is a triolwhich means more than one OH group. -triol suffix is added to the end of the parent alcohol and numbers are added as a prefix to indicate the positions of the -OH groups. Hence; IUPAC name for the C3H8O3 is1,2,3-propanthriol.

Expert Solution

Interpretation Introduction

(e)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 5

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1-ethyl-2-methylcyclopentanol.

Explanation of Solution

( C8H16O ) contains five membered main carbon ring and OH group is directly connected to the cylopentane ring. Ethyl group is connected to the cylopentane ring via 1^s^t position and methyl group is connected via 2ⁿ^d position. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 1-ethyl-2-methylcyclopentanol.

Expert Solution

Interpretation Introduction

(f)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 6

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3,4-dimethylcyclohexanol.

Explanation of Solution

( C8H16O ) contains six membered main carbon ring and OH group is directly connected to the cylohexane ring. Methyl groups are connected to the cyclohexane ring through 3^r^d and 4^t^h positions. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 3,4-dimethylcyclohexanol.

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Answer 3

Textbook Question

Chapter 14, Problem 14.42P

Give the IUAPC name for each alcohol.
Chapter 14, Problem 14.42P, Give the IUAPC name for each alcohol. , example 1

Expert Solution

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 1

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

6-methyl-3-heptanol.

Explanation of Solution

C8H18O contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 6^t^h position and OH group is connected to the main carbon chain via 3^r^d position. Hence; IUPAC name for the C8H18O is 6-methyl-3-heptanol.

Expert Solution

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 2

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

2-ethylpentanol.

Explanation of Solution

( C7H16O ) contains five membered main carbon chain. Ethyl group is connected to the main carbon chain from the 2ⁿ^d position and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H16O is 2-ethylpentanol.

Expert Solution

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 3

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3-methylheptanol.

Explanation of Solution

( C7H18O ) contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 3^r^dposition and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H18O is 3-methylheptanol.

Expert Solution

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 4

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1,2,3-propantriol.

Explanation of Solution

( C3H8O3 ) contains three membered main carbon chain. Each carbon connects to a OH group and this C3H8O3 is a triolwhich means more than one OH group. -triol suffix is added to the end of the parent alcohol and numbers are added as a prefix to indicate the positions of the -OH groups. Hence; IUPAC name for the C3H8O3 is1,2,3-propanthriol.

Expert Solution

Interpretation Introduction

(e)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 5

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1-ethyl-2-methylcyclopentanol.

Explanation of Solution

( C8H16O ) contains five membered main carbon ring and OH group is directly connected to the cylopentane ring. Ethyl group is connected to the cylopentane ring via 1^s^t position and methyl group is connected via 2ⁿ^d position. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 1-ethyl-2-methylcyclopentanol.

Expert Solution

Interpretation Introduction

(f)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 6

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3,4-dimethylcyclohexanol.

Explanation of Solution

( C8H16O ) contains six membered main carbon ring and OH group is directly connected to the cylohexane ring. Methyl groups are connected to the cyclohexane ring through 3^r^d and 4^t^h positions. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 3,4-dimethylcyclohexanol.

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Answer 4

Textbook Question

Chapter 14, Problem 14.42P

Give the IUAPC name for each alcohol.
Chapter 14, Problem 14.42P, Give the IUAPC name for each alcohol. , example 1

Expert Solution

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 1

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

6-methyl-3-heptanol.

Explanation of Solution

C8H18O contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 6^t^h position and OH group is connected to the main carbon chain via 3^r^d position. Hence; IUPAC name for the C8H18O is 6-methyl-3-heptanol.

Expert Solution

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 2

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

2-ethylpentanol.

Explanation of Solution

( C7H16O ) contains five membered main carbon chain. Ethyl group is connected to the main carbon chain from the 2ⁿ^d position and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H16O is 2-ethylpentanol.

Expert Solution

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 3

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3-methylheptanol.

Explanation of Solution

( C7H18O ) contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 3^r^dposition and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H18O is 3-methylheptanol.

Expert Solution

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 4

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1,2,3-propantriol.

Explanation of Solution

( C3H8O3 ) contains three membered main carbon chain. Each carbon connects to a OH group and this C3H8O3 is a triolwhich means more than one OH group. -triol suffix is added to the end of the parent alcohol and numbers are added as a prefix to indicate the positions of the -OH groups. Hence; IUPAC name for the C3H8O3 is1,2,3-propanthriol.

Expert Solution

Interpretation Introduction

(e)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 5

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1-ethyl-2-methylcyclopentanol.

Explanation of Solution

( C8H16O ) contains five membered main carbon ring and OH group is directly connected to the cylopentane ring. Ethyl group is connected to the cylopentane ring via 1^s^t position and methyl group is connected via 2ⁿ^d position. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 1-ethyl-2-methylcyclopentanol.

Expert Solution

Interpretation Introduction

(f)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 6

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3,4-dimethylcyclohexanol.

Explanation of Solution

( C8H16O ) contains six membered main carbon ring and OH group is directly connected to the cylohexane ring. Methyl groups are connected to the cyclohexane ring through 3^r^d and 4^t^h positions. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 3,4-dimethylcyclohexanol.

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Answer 5

Textbook Question

Answer 6

Textbook Question

Answer 7

Expert Solution

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 1

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

6-methyl-3-heptanol.

Explanation of Solution

C8H18O contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 6^t^h position and OH group is connected to the main carbon chain via 3^r^d position. Hence; IUPAC name for the C8H18O is 6-methyl-3-heptanol.

Expert Solution

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 2

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

2-ethylpentanol.

Explanation of Solution

( C7H16O ) contains five membered main carbon chain. Ethyl group is connected to the main carbon chain from the 2ⁿ^d position and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H16O is 2-ethylpentanol.

Expert Solution

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 3

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3-methylheptanol.

Explanation of Solution

( C7H18O ) contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 3^r^dposition and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H18O is 3-methylheptanol.

Expert Solution

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 4

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1,2,3-propantriol.

Explanation of Solution

( C3H8O3 ) contains three membered main carbon chain. Each carbon connects to a OH group and this C3H8O3 is a triolwhich means more than one OH group. -triol suffix is added to the end of the parent alcohol and numbers are added as a prefix to indicate the positions of the -OH groups. Hence; IUPAC name for the C3H8O3 is1,2,3-propanthriol.

Expert Solution

Interpretation Introduction

(e)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 5

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1-ethyl-2-methylcyclopentanol.

Explanation of Solution

( C8H16O ) contains five membered main carbon ring and OH group is directly connected to the cylopentane ring. Ethyl group is connected to the cylopentane ring via 1^s^t position and methyl group is connected via 2ⁿ^d position. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 1-ethyl-2-methylcyclopentanol.

Expert Solution

Interpretation Introduction

(f)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 6

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3,4-dimethylcyclohexanol.

Explanation of Solution

( C8H16O ) contains six membered main carbon ring and OH group is directly connected to the cylohexane ring. Methyl groups are connected to the cyclohexane ring through 3^r^d and 4^t^h positions. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 3,4-dimethylcyclohexanol.

Answer 8

Expert Solution

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 1

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

6-methyl-3-heptanol.

Explanation of Solution

C8H18O contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 6^t^h position and OH group is connected to the main carbon chain via 3^r^d position. Hence; IUPAC name for the C8H18O is 6-methyl-3-heptanol.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 1

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer 13

Answer to Problem 14.42P

6-methyl-3-heptanol.

Answer 14

Explanation of Solution

C8H18O contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 6^t^h position and OH group is connected to the main carbon chain via 3^r^d position. Hence; IUPAC name for the C8H18O is 6-methyl-3-heptanol.

Answer 15

Expert Solution

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 2

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

2-ethylpentanol.

Explanation of Solution

( C7H16O ) contains five membered main carbon chain. Ethyl group is connected to the main carbon chain from the 2ⁿ^d position and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H16O is 2-ethylpentanol.

Answer 16

Expert Solution

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 2

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer 20

Answer to Problem 14.42P

2-ethylpentanol.

Answer 21

Explanation of Solution

( C7H16O ) contains five membered main carbon chain. Ethyl group is connected to the main carbon chain from the 2ⁿ^d position and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H16O is 2-ethylpentanol.

Answer 22

Expert Solution

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 3

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3-methylheptanol.

Explanation of Solution

( C7H18O ) contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 3^r^dposition and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H18O is 3-methylheptanol.

Answer 23

Expert Solution

Answer 24

Expert Solution

Answer 25

Expert Solution

Answer 26

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 3

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer 27

Answer to Problem 14.42P

3-methylheptanol.

Answer 28

Explanation of Solution

( C7H18O ) contains seven membered main carbon chain. Methyl group is connected to the main carbon chain from the 3^r^dposition and OH group is connected to the main carbon chain via 1^s^t position. Hence; IUPAC name for the C7H18O is 3-methylheptanol.

Answer 29

Expert Solution

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 4

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1,2,3-propantriol.

Explanation of Solution

( C3H8O3 ) contains three membered main carbon chain. Each carbon connects to a OH group and this C3H8O3 is a triolwhich means more than one OH group. -triol suffix is added to the end of the parent alcohol and numbers are added as a prefix to indicate the positions of the -OH groups. Hence; IUPAC name for the C3H8O3 is1,2,3-propanthriol.

Answer 30

Expert Solution

Answer 31

Expert Solution

Answer 32

Expert Solution

Answer 33

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 4

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer 34

Answer to Problem 14.42P

1,2,3-propantriol.

Answer 35

Explanation of Solution

( C3H8O3 ) contains three membered main carbon chain. Each carbon connects to a OH group and this C3H8O3 is a triolwhich means more than one OH group. -triol suffix is added to the end of the parent alcohol and numbers are added as a prefix to indicate the positions of the -OH groups. Hence; IUPAC name for the C3H8O3 is1,2,3-propanthriol.

Answer 36

Expert Solution

Interpretation Introduction

(e)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 5

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

1-ethyl-2-methylcyclopentanol.

Explanation of Solution

( C8H16O ) contains five membered main carbon ring and OH group is directly connected to the cylopentane ring. Ethyl group is connected to the cylopentane ring via 1^s^t position and methyl group is connected via 2ⁿ^d position. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 1-ethyl-2-methylcyclopentanol.

Answer 37

Expert Solution

Answer 38

Expert Solution

Answer 39

Expert Solution

Answer 40

Interpretation Introduction

(e)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 5

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer 41

Answer to Problem 14.42P

1-ethyl-2-methylcyclopentanol.

Answer 42

Explanation of Solution

( C8H16O ) contains five membered main carbon ring and OH group is directly connected to the cylopentane ring. Ethyl group is connected to the cylopentane ring via 1^s^t position and methyl group is connected via 2ⁿ^d position. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 1-ethyl-2-methylcyclopentanol.

Answer 43

Expert Solution

Interpretation Introduction

(f)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 6

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer to Problem 14.42P

3,4-dimethylcyclohexanol.

Explanation of Solution

( C8H16O ) contains six membered main carbon ring and OH group is directly connected to the cylohexane ring. Methyl groups are connected to the cyclohexane ring through 3^r^d and 4^t^h positions. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 3,4-dimethylcyclohexanol.

Answer 44

Expert Solution

Answer 45

Expert Solution

Answer 46

Expert Solution

Answer 47

Interpretation Introduction

(f)

Interpretation:

The IUPAC name of the following compound should be determined:

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 14, Problem 14.42P , additional homework tip 6

Concept Introduction:

Alcohols are the organic molecules which have OH group bonded to a tetrahedral carbon atom.

Longest carbon chain containing the carbon bonded to the OH group is named as an alkane and -e of the alkane replaced by the suffix -ol.

Numbering of main carbon chain is done in such a way so that OH group gets the lowest number.

When OH group is bonded to a ring, the ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Compounds which contains two OH groups are named as diols and when in nomenclature, -diol suffix is added to the end of the parent alcohol and position of the OH groups are used as prefix to indicate the location of the two OH groups.

Answer 48

Answer to Problem 14.42P

3,4-dimethylcyclohexanol.

Answer 49

Explanation of Solution

( C8H16O ) contains six membered main carbon ring and OH group is directly connected to the cylohexane ring. Methyl groups are connected to the cyclohexane ring through 3^r^d and 4^t^h positions. Numbering of the carbon ring is done according to the nomenclature rules. The ring is numbered beginning with the OH group and the 1 is normally omitted from the name. The ring is numbered in clockwise or anticlockwise by giving the lowest number to the next substitute.

Hence; IUPAC name of the ( C8H16O ) is 3,4-dimethylcyclohexanol.