(a) Interpretation: The following molecule should be named: Concept Introduction: Ethers are molecules which have two alkyl groups bonded to the oxygen atom. Simple ethers named based on their structure. In ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group. When naming more complex ethers according to the IUPAC nomenclature ; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should named as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix.Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

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Answer 1

Question

Chapter 14, Problem 14.38P

Interpretation Introduction

(a)

Interpretation:

The following molecule should be named:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

In ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should named as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix.Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

The following molecule should be named:

Concept Introduction:

Organic compounds which contains a sulfhydryl group (SH) bonded to a tetrahedral carbon is known as thiols. In the periodic table, sulfur is placed directly below to the oxygen, thiols can be considered as sulfur analogs of alcohols.

When naming the thiols, parent hydrocarbon is named as alkane and at the end -thiol suffix should be added. Main carbon chain is numbered by giving the SH group the lower number.

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

A chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.

Answer 2

Question

Chapter 14, Problem 14.38P

Interpretation Introduction

(a)

Interpretation:

The following molecule should be named:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

In ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should named as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix.Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

The following molecule should be named:

Concept Introduction:

Organic compounds which contains a sulfhydryl group (SH) bonded to a tetrahedral carbon is known as thiols. In the periodic table, sulfur is placed directly below to the oxygen, thiols can be considered as sulfur analogs of alcohols.

When naming the thiols, parent hydrocarbon is named as alkane and at the end -thiol suffix should be added. Main carbon chain is numbered by giving the SH group the lower number.

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Answer 3

Question

Chapter 14, Problem 14.38P

Interpretation Introduction

(a)

Interpretation:

The following molecule should be named:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

In ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should named as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix.Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

The following molecule should be named:

Concept Introduction:

Organic compounds which contains a sulfhydryl group (SH) bonded to a tetrahedral carbon is known as thiols. In the periodic table, sulfur is placed directly below to the oxygen, thiols can be considered as sulfur analogs of alcohols.

When naming the thiols, parent hydrocarbon is named as alkane and at the end -thiol suffix should be added. Main carbon chain is numbered by giving the SH group the lower number.

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Answer 4

Question

Chapter 14, Problem 14.38P

Interpretation Introduction

(a)

Interpretation:

The following molecule should be named:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

In ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should named as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix.Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

The following molecule should be named:

Concept Introduction:

Organic compounds which contains a sulfhydryl group (SH) bonded to a tetrahedral carbon is known as thiols. In the periodic table, sulfur is placed directly below to the oxygen, thiols can be considered as sulfur analogs of alcohols.

When naming the thiols, parent hydrocarbon is named as alkane and at the end -thiol suffix should be added. Main carbon chain is numbered by giving the SH group the lower number.

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Answer 5

Chapter 14, Problem 14.38P

Interpretation Introduction

(a)

Interpretation:

The following molecule should be named:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

In ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should named as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix.Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

The following molecule should be named:

Concept Introduction:

Organic compounds which contains a sulfhydryl group (SH) bonded to a tetrahedral carbon is known as thiols. In the periodic table, sulfur is placed directly below to the oxygen, thiols can be considered as sulfur analogs of alcohols.

When naming the thiols, parent hydrocarbon is named as alkane and at the end -thiol suffix should be added. Main carbon chain is numbered by giving the SH group the lower number.

Answer 6

Chapter 14, Problem 14.38P

Interpretation Introduction

(a)

Interpretation:

The following molecule should be named:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

In ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should named as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix.Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 7

Chapter 14, Problem 14.38P

Interpretation Introduction

(a)

Interpretation:

The following molecule should be named:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

In ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should named as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix.Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The following molecule should be named:

Concept Introduction:

Organic compounds which contains a sulfhydryl group (SH) bonded to a tetrahedral carbon is known as thiols. In the periodic table, sulfur is placed directly below to the oxygen, thiols can be considered as sulfur analogs of alcohols.

When naming the thiols, parent hydrocarbon is named as alkane and at the end -thiol suffix should be added. Main carbon chain is numbered by giving the SH group the lower number.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The following molecule should be named:

Concept Introduction:

Organic compounds which contains a sulfhydryl group (SH) bonded to a tetrahedral carbon is known as thiols. In the periodic table, sulfur is placed directly below to the oxygen, thiols can be considered as sulfur analogs of alcohols.

When naming the thiols, parent hydrocarbon is named as alkane and at the end -thiol suffix should be added. Main carbon chain is numbered by giving the SH group the lower number.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.2P Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Prob. 14.5P Ch. 14.3 - Prob. 14.6P Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.9P Ch. 14.5 - Prob. 14.10P

Solution Summary: The author explains that ethyl ethers are molecules with two alkyl groups bonded to the oxygen atom.

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