(a) Interpretation: An acceptable name for the following ether should be determined: Concept Introduction: Ethers are molecules which have two alkyl groups bonded to the oxygen atom. Simple ethers named based on their structure. When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group. When naming more complex ethers according to the IUPAC nomenclature ; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

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Answer 1

Question

Chapter 14, Problem 14.45P

Interpretation Introduction

(a)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(c)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

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11 1 Which one of the following compounds would show a proton NMR signal at the highest chemical shift? (7pts) cl @amitabh CI CI d) Cl CICI

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Answer 2

Question

Chapter 14, Problem 14.45P

Interpretation Introduction

(a)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(c)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

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Answer 3

Question

Chapter 14, Problem 14.45P

Interpretation Introduction

(a)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(c)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

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Answer 4

Question

Chapter 14, Problem 14.45P

Interpretation Introduction

(a)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(c)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

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Answer 5

Chapter 14, Problem 14.45P

Interpretation Introduction

(a)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(b)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Interpretation Introduction

(c)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 6

Chapter 14, Problem 14.45P

Interpretation Introduction

(a)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 7

Chapter 14, Problem 14.45P

Interpretation Introduction

(a)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 8

Interpretation Introduction

(b)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 9

Interpretation Introduction

(b)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 10

Interpretation Introduction

(c)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 11

Interpretation Introduction

(c)

Interpretation:

An acceptable name for the following ether should be determined:

Concept Introduction:

Ethers are molecules which have two alkyl groups bonded to the oxygen atom.

Simple ethers named based on their structure.

When ether nomenclature, both alkyl groups are named and arranged them according to the alphabetical order and at the end of the name word 'ether' should be added. Ethers which have identical alkyl groups, prefix di- should be added to the alkyl group.

When naming more complex ethers according to the IUPAC nomenclature; one alkyl group is named as a hydrocarbon chain and the other part is named as a part of substituent bonded to that chain. The simpler alkyl group with the oxygen atom should name as an alkoxy substituent and the -yl suffix of the alkyl replaced with- oxy suffix. Remaining longest alkyl chain is named as an alkane by considering the alkoxy group as a substituent bonded to the main carbon chain.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.2P Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Prob. 14.5P Ch. 14.3 - Prob. 14.6P Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.9P Ch. 14.5 - Prob. 14.10P

Solution Summary: The author explains that ethers are molecules which have two alkyl groups bonded to the oxygen atom.

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