(a) Interpretation: The disulfide formed on oxidizing the following thiol should be determined: Concept Introduction: Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon. Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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Answer 1

Question

Chapter 14, Problem 14.81P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major contributor in each case, or if they are equivalent (45) (2) -PH2 سمة مد

A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3

1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

Answer 2

Question

Chapter 14, Problem 14.81P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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Answer 3

Question

Chapter 14, Problem 14.81P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 14.81P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

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Answer 5

Chapter 14, Problem 14.81P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 6

Chapter 14, Problem 14.81P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 7

Chapter 14, Problem 14.81P

Interpretation Introduction

(a)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The disulfide formed on oxidizing the following thiol should be determined:

CH3(CH2)4SH

Concept Introduction:

Thiols are organic compounds which contains a sulfhydryl group (SH group) bonded to a tetrahedral carbon.

Reaction of thiols with oxidizing agent will form disulfides and the reaction is known as an oxidation reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 14.1 - Prob. 14.1P Ch. 14.2 - Prob. 14.2P Ch. 14.2 - Classify each hydroxyl group in sorbitol as 1°,...Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Prob. 14.5P Ch. 14.3 - Prob. 14.6P Ch. 14.3 - Give the structure corresponding to each name a....Ch. 14.5 - Draw the products formed when each alcohol is...Ch. 14.5 - Prob. 14.9P Ch. 14.5 - Prob. 14.10P

Solution Summary: The author explains that thiols are considered as sulfur analogs of alcohols since S is placed directly below to the oxygen in the periodic table.

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