
(a)
Interpretation:
The effect of addition of catalyst on amount of carbon monoxide in given reaction has to be explained.
Concept introduction:
Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it resets to counteract the effect of disturbance.
(b)
Interpretation:
The effect of increase in temperature of given reaction results in change in concentration of carbon monoxide has to be explained.
Concept introduction:
Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it resets to counteract the effect of disturbance.
Effect of change in temperature:
Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.
Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.
(c)
Interpretation:
The effect of increase in pressure of the given reaction results in change in concentration of carbon monoxide has to be explained.
Concept introduction:
Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it resetss to counteract the effect of disturbance.
Effect of change in pressure:
- According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.
- According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.
(d)
Interpretation:
The effect of increase in pressure by adding argon of the given reaction has to be explained.
Concept introduction:
Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it resets to counteract the effect of disturbance.
Effect of change in pressure:
- According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.
- According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.
(e)
Interpretation:
The effect of increase in pressure by adding oxygen gas of the given reaction results in change in concentration of carbon monoxide has to be explained.
Concept introduction:
Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it resets to counteract the effect of disturbance.
Effect of change in pressure:
- According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.
- According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.

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Chapter 13 Solutions
General Chemistry: Atoms First
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