General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 13, Problem 13.136MP
For the decomposition reaction PCl5(g) ⇌ PCl3(g) + Cl2(g), Kp = 381 at 600 K and Kc = 46.9 at 700 K.
- (a) Is the reaction endothermic or exothermic? Explain. Does your answer agree with what you would predict based on bond energies?
- (b) If 1.25 g of PCl5 is introduced into an evacuated 0.500 L flask at 700 K and the decomposition reaction is allowed to reach equilibrium, what percent of the PC15 will decompose and what will be the total pressure in the flask?
- (c) Write electron-dot structures for PC15 and PC13, and indicate whether these molecules have a dipole moment. Explain.
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Chapter 13 Solutions
General Chemistry: Atoms First
Ch. 13.2 - The oxidation of sulfur dioxide to give sulfur...Ch. 13.2 - The following equilibrium concentrations were...Ch. 13.2 - Prob. 13.3PCh. 13.2 - The following pictures represent mixtures that...Ch. 13.3 - Prob. 13.5PCh. 13.4 - In the industrial synthesis of hydrogen, mixtures...Ch. 13.4 - Prob. 13.7PCh. 13.5 - Prob. 13.8PCh. 13.6 - Prob. 13.9PCh. 13.6 - Prob. 13.10P
Ch. 13.6 - Prob. 13.11CPCh. 13.6 - Prob. 13.12PCh. 13.6 - Prob. 13.13PCh. 13.6 - Prob. 13.14PCh. 13.6 - Prob. 13.15PCh. 13.6 - Prob. 13.16PCh. 13.8 - Prob. 13.17PCh. 13.9 - Prob. 13.18PCh. 13.9 - Prob. 13.19CPCh. 13.10 - Prob. 13.20PCh. 13.10 - Prob. 13.21PCh. 13.10 - Prob. 13.22CPCh. 13.11 - Prob. 13.23PCh. 13.11 - Prob. 13.24PCh. 13.11 - Prob. 13.25PCh. 13 - Consider the interconversion of A molecules (red...Ch. 13 - Prob. 13.27CPCh. 13 - Prob. 13.28CPCh. 13 - Prob. 13.29CPCh. 13 - Prob. 13.30CPCh. 13 - Prob. 13.31CPCh. 13 - Prob. 13.32CPCh. 13 - Prob. 13.33CPCh. 13 - Prob. 13.34CPCh. 13 - Prob. 13.35CPCh. 13 - Prob. 13.36CPCh. 13 - The following pictures represent the initial and...Ch. 13 - Prob. 13.38SPCh. 13 - Prob. 13.39SPCh. 13 - Prob. 13.40SPCh. 13 - Prob. 13.41SPCh. 13 - Prob. 13.42SPCh. 13 - Prob. 13.43SPCh. 13 - Prob. 13.44SPCh. 13 - Prob. 13.45SPCh. 13 - Prob. 13.46SPCh. 13 - Prob. 13.47SPCh. 13 - Prob. 13.48SPCh. 13 - Prob. 13.49SPCh. 13 - Prob. 13.50SPCh. 13 - Prob. 13.51SPCh. 13 - Prob. 13.52SPCh. 13 - Prob. 13.53SPCh. 13 - Prob. 13.54SPCh. 13 - Prob. 13.55SPCh. 13 - Prob. 13.56SPCh. 13 - Prob. 13.57SPCh. 13 - Prob. 13.58SPCh. 13 - Prob. 13.59SPCh. 13 - Prob. 13.60SPCh. 13 - Prob. 13.61SPCh. 13 - Prob. 13.62SPCh. 13 - Prob. 13.63SPCh. 13 - Prob. 13.64SPCh. 13 - Prob. 13.65SPCh. 13 - Prob. 13.66SPCh. 13 - Prob. 13.67SPCh. 13 - Prob. 13.68SPCh. 13 - Prob. 13.69SPCh. 13 - Prob. 13.70SPCh. 13 - Prob. 13.71SPCh. 13 - Prob. 13.72SPCh. 13 - Prob. 13.73SPCh. 13 - Gaseous indium dihydride is formed from the...Ch. 13 - Prob. 13.75SPCh. 13 - Prob. 13.76SPCh. 13 - Prob. 13.77SPCh. 13 - Prob. 13.78SPCh. 13 - Prob. 13.79SPCh. 13 - Prob. 13.80SPCh. 13 - Prob. 13.81SPCh. 13 - The value of Kc for the reaction of acetic acid...Ch. 13 - In a basic aqueous solution, chloromethane...Ch. 13 - Prob. 13.84SPCh. 13 - Prob. 13.85SPCh. 13 - Prob. 13.86SPCh. 13 - Prob. 13.87SPCh. 13 - Prob. 13.88SPCh. 13 - Prob. 13.89SPCh. 13 - Prob. 13.90SPCh. 13 - Prob. 13.91SPCh. 13 - Prob. 13.92SPCh. 13 - Consider the endothermic reaction Fe3+ (aq) + Cl...Ch. 13 - Prob. 13.94SPCh. 13 - Prob. 13.95SPCh. 13 - Prob. 13.96SPCh. 13 - Prob. 13.97SPCh. 13 - Prob. 13.98CHPCh. 13 - Prob. 13.99CHPCh. 13 - Prob. 13.100CHPCh. 13 - Prob. 13.101CHPCh. 13 - Prob. 13.102CHPCh. 13 - Prob. 13.103CHPCh. 13 - Prob. 13.104CHPCh. 13 - Prob. 13.105CHPCh. 13 - Refining petroleum involves cracking large...Ch. 13 - Prob. 13.107CHPCh. 13 - Prob. 13.108CHPCh. 13 - Prob. 13.109CHPCh. 13 - Prob. 13.110CHPCh. 13 - At 1000 K, Kp = 2.1 106 and H = 107.7 kJ for the...Ch. 13 - Consider the gas-phase decomposition of NOBr: 2...Ch. 13 - At 100C, Kc = 4.72 for the reaction 2 NO2(g) ...Ch. 13 - Prob. 13.114CHPCh. 13 - Prob. 13.115CHPCh. 13 - Prob. 13.116CHPCh. 13 - Prob. 13.117CHPCh. 13 - Prob. 13.118CHPCh. 13 - Prob. 13.119CHPCh. 13 - Prob. 13.120CHPCh. 13 - Prob. 13.121CHPCh. 13 - Prob. 13.122CHPCh. 13 - Prob. 13.123CHPCh. 13 - Prob. 13.124CHPCh. 13 - Prob. 13.125MPCh. 13 - Prob. 13.126MPCh. 13 - The equilibrium constant Kc for the gas-phase...Ch. 13 - Prob. 13.128MPCh. 13 - Prob. 13.129MPCh. 13 - Prob. 13.130MPCh. 13 - Prob. 13.131MPCh. 13 - Prob. 13.132MPCh. 13 - Consider the sublimation of mothballs at 27C in a...Ch. 13 - Prob. 13.134MPCh. 13 - Prob. 13.135MPCh. 13 - For the decomposition reaction PCl5(g) PCl3(g) +...Ch. 13 - Prob. 13.137MP
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