The change in number of moles of carbon dioxide while adding solid NaHCO 3 has to be explained. Concept introduction: Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

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Answer 1

Question

Chapter 13, Problem 13.103CHP

(a)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding solid NaHCO3 has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(b)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding water vapor has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(c)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while decreasing the volume of container has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in pressure:

According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.

According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.

(d)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while increasing temperature has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in temperature:

Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.

Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.

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81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

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Answer 2

Question

Chapter 13, Problem 13.103CHP

(a)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding solid NaHCO3 has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(b)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding water vapor has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(c)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while decreasing the volume of container has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in pressure:

According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.

According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.

(d)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while increasing temperature has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in temperature:

Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.

Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.

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Answer 3

Question

Chapter 13, Problem 13.103CHP

(a)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding solid NaHCO3 has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(b)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding water vapor has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(c)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while decreasing the volume of container has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in pressure:

According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.

According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.

(d)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while increasing temperature has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in temperature:

Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.

Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.

Expert Solution & Answer

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Answer 4

Question

Chapter 13, Problem 13.103CHP

(a)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding solid NaHCO3 has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(b)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding water vapor has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(c)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while decreasing the volume of container has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in pressure:

According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.

According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.

(d)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while increasing temperature has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in temperature:

Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.

Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 13, Problem 13.103CHP

(a)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding solid NaHCO3 has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(b)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding water vapor has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

(c)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while decreasing the volume of container has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in pressure:

According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.

According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.

(d)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while increasing temperature has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in temperature:

Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.

Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.

Answer 6

Chapter 13, Problem 13.103CHP

(a)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding solid NaHCO3 has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Answer 7

Chapter 13, Problem 13.103CHP

(a)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding solid NaHCO3 has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding water vapor has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while adding water vapor has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while decreasing the volume of container has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in pressure:

According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.

According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while decreasing the volume of container has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in pressure:

According to Le Chatelier's principle, increase in pressure leads to flow of reaction in direction where number of moles is less.

According to Le Chatelier's principle, decrease in pressure leads to flow of reaction in direction where number of moles is more.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while increasing temperature has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in temperature:

Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.

Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The change in number of moles of carbon dioxide while increasing temperature has to be explained.

Concept introduction:

Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.

Effect of change in temperature:

Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.

Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 13.2 - The oxidation of sulfur dioxide to give sulfur...Ch. 13.2 - The following equilibrium concentrations were...Ch. 13.2 - Prob. 13.3P Ch. 13.2 - The following pictures represent mixtures that...Ch. 13.3 - Prob. 13.5P Ch. 13.4 - In the industrial synthesis of hydrogen, mixtures...Ch. 13.4 - Prob. 13.7P Ch. 13.5 - Prob. 13.8P Ch. 13.6 - Prob. 13.9P Ch. 13.6 - Prob. 13.10P

Solution Summary: The author explains Le Chatelier's principle that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, it resets to counteract the effect of disturbance.

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