
(a)
Interpretation:
The equilibrium constant
Concept introduction:
Equilibrium constant
In gas phase reactions, partial pressure is used to write equilibrium equation than molar concentration. Equilibrium constant
Consider the reaction where A reacts to give B.
On rearranging,
Where,
The pressure of each species of ideal gas and its molar concentration are directly proportional to each other.
In same way
Where,
R is gas constant
T is absolute temperature
(b)
Interpretation:
The equilibrium constant
Concept introduction:
Equilibrium constant
In gas phase reactions, partial pressure is used to write equilibrium equation than molar concentration. Equilibrium constant
Consider the reaction where A reacts to give B.
On rearranging,
Where,
The pressure of each species of ideal gas and its molar concentration are directly proportional to each other.
In same way
Where,
R is gas constant
T is absolute temperature
(c)
Interpretation:
The given reaction is endothermic or exothermic reaction has to be explained.
Concept introduction:
Le Chatelier's principle states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.
Effect of change in temperature:
Endothermic reaction: In this reaction increase in temperature which is absorbed in reactant side, the reaction occurs in a way to relieve the stress in reactant side. The reaction occurs along the direction of product side and increases equilibrium constant.
Exothermic reaction: In this reaction increase in temperature which is released in product side, the reaction occurs in a way to relieve the stress in product side. The reaction occurs along the direction of reactant side and decreases equilibrium constant.

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Chapter 13 Solutions
General Chemistry: Atoms First
- Predict the products of this organic reaction: OH + NaOH A? Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click and drag to start drawing a structure. ✓ Sarrow_forwardPredict the products of this organic reaction: CH3-C-O-CH2-CH2-C-CH3 + H₂O ? A Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click anywhere to draw the first atom of your structure. :☐ darrow_forwardDE d. Draw an arrow pushing mechanism for the following IN O CI N fo 人 P Polle DELL prt sc home end ins F5 F6 F7 F8 F9 F10 F11 F12arrow_forward
- Predict the products of this organic reaction: + H₂O H* ? A Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click and drag to start drawing a structure.arrow_forwardPredict the major organic products of the reaction below and draw them on right side of the arrow. If there will be no significant reaction, check the box below the drawing area instead. C Cl CH, OH There will be no significant reaction. + pyridine G Click and drag to start drawing a structure.arrow_forwardWhat is the missing reactant in this organic reaction? H R+ H2O Δ OH 0= CH3-CH-O-CH3 + CH3-C-OH Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. No Answer Click anywhere to draw the first atom of your structure. dyarrow_forward
- You are trying to determine whether the following organic reaction can be done in a single synthesis step. If so, add any missing reagents or conditions in the drawing area below. If it isn't possible to do this reaction in a single synthesis step, check the box below the drawing area instead. Note for advanced students: if you have a choice of reagents to add, you should choose the least reactive and most economical reagents possible. Cl It isn't possible to do this reaction in a single synthesis step. + T OHarrow_forwardPredict the products of this organic reaction: CH3 O CH3-CH-C-O-CH2-CH2-CH3 + H₂OH+ Η ? A Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click anywhere to draw the first atom of your structure.arrow_forward€ CH3-CH-C-O-CH2-CH2-CH3 + NaOH A? Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. Predict the products of this organic reaction: CH3 O Click anywhere to draw the first atom of your structure. No reaction ✓ Garrow_forward
- A molecule can have a temporary or permanent depending on the structure and the way the electrons can move. True Falsearrow_forwardedict the products of this organic reaction: CH3 O A CH3-CH-C-NH2 + H2O + HCI ? Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. If there's more than one product, draw them in any arrangement you like, so long as they aren't touching. If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. Click anywhere to draw the first atom of your structure. No Reaction planation Check 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center +arrow_forwardDraw the mechanism for the following reaction: OH A few notes: CI O • You may assume that each reagent is present in whatever amount you need to draw your mechanism. • To save you some time, one of the starting materials has been copied into the first step of the drawing area. AP Add/Remove step Cl Click and drag to start drawing a structure.arrow_forward
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