Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 13, Problem 13.54P
13-54 Styrene reacts with bromine to give a compound with the molecular formula CgH8Br2. Draw a struc tural formula for this compound.
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Lewis Structure, Hybridization & Molecular Geometry
a) Draw the Lewis Structure of the molecules; Label the hybridization of each carbon atom;
Predict the approximate molecular geometry around each carbon atom.
CH3CHO
CH3CN
b) Draw the Lewis Structure of Nitromethane; Predict the approximate molecular geometry
around the nitrogen atom.
CH3NO2
c) Draw the Lewis Structure; Label the hybridization of the boron atom; Predict the
approximate molecular geometry.
BF3
BF4
a. The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 " is
best described as a hybrid of several contributing resonance forms, two of which
are shown here.
HO
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HO
+
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Bicarbonate is crucial for the control of body pH (for example, blood pH
7.4). A more self-indulgent use is in baking soda, where it serves as a
source of CO2 CO2 gas, which gives bread and pastry their fluffy
constituency.
(i) Draw at least one additional resonance form.
=
(ii) Using curved "electron-pushing" arrows, show how these Lewis structures may
be interconverted by movement of electron pairs. (iii) Determine which form or
forms will be the major contributor(s) to the real structure of bicarbonate,
explaining your answer on the basis of the criteria in Section 1-5.
Calibri
11
+
BIL
NAME: Jaylena M
A student is investigating the ctect of volume on pressure during a lab activity. The student uses the
following volumes (mL). 12, 13, 14, 16, 17, 18, 19, 20, 21, 22, 23, 24, 26, 28, 30, 33, 34, 35, 38, 40, 42, 44.
46, and 50. As the volume changed they measured the following pressures (atm) 11.0, 10.5, 10.0, 9.2.
8.5, 78, 75, 7.0, 6.8, 6.5, 6.0, 5.9, 5.5, 5.0, 4.8, 4.5, 4.2, 3.9, 3.8, 3.5, 3.3, 3.2, 3.0, 2.9.
What is the independent variable? Volume Imla
What is the dependent variable? Pressure Jatm
Use the data and make a PROPER data table.
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110
Chapter 13 Solutions
Introduction to General, Organic and Biochemistry
Ch. 13.2 - Prob. 13.1PCh. 13 - Answer true or false. Alkenes, alkynes, and arenes...Ch. 13 - 13-3 What is the difference in structure between a...Ch. 13 - 13-4 Define aromatic compound.Ch. 13 - 13-5 Why are alkenes, alkynes, and aromatic...Ch. 13 - 13-B Do aromatic rings have double bonds? Are they...Ch. 13 - 13-7 Can an aromatic compound be a saturated...Ch. 13 - Draw at least two structural formulas for each of...Ch. 13 - 13-9 Write a structural formula and the name for...Ch. 13 - 13-10 Account for the fact that the six-membered...
Ch. 13 - 13-11 Explain why the compound 1,4-dichlorobenzene...Ch. 13 - 13-12 One analogy often used to explain the...Ch. 13 - 13-13 Answer true or false. A phenyl group has the...Ch. 13 - Prob. 13.14PCh. 13 - 13-15 Draw structural formulas for these compounds...Ch. 13 - 13-16 We say that naphthalene, anthracene,...Ch. 13 - 13-17 Following is the structural formula of...Ch. 13 - 13-18 Answer true or false. Benzene does not...Ch. 13 - 13-19 Suppose you have unlabeled bottles of...Ch. 13 - 13-20 Three products with the molecular formula...Ch. 13 - 13-21 The reaction of bromine with toluene in the...Ch. 13 - 13-22 What reagents and/or catalysts are necessary...Ch. 13 - 13-23 What reagents and/or catalysts are necessary...Ch. 13 - Prob. 13.24PCh. 13 - 13-25 Answer true or false. (a) Phenols and...Ch. 13 - 13-26 Both phenol and cyclohexanol are only...Ch. 13 - 13-27 Define autoxidation.Ch. 13 - 13*28 Autoxidation is described as a radical-chain...Ch. 13 - 13-29 Show that if you add Steps 2a and 2b of the...Ch. 13 - 13-30 How does vitamin E function as an...Ch. 13 - 13-31 What structural features are common to...Ch. 13 - 13*32 Black-and-white photography is a commercial...Ch. 13 - 13-33 Following is the structural formula of...Ch. 13 - 13-34 (Chemical Connections 13A) From what parts...Ch. 13 - Prob. 13.35PCh. 13 - 13-36 (Chemical Connections 13A, Would you expect...Ch. 13 - Prob. 13.37PCh. 13 - 13-38 (Chemical Connections 13A) What is meant by...Ch. 13 - 13-39 (Chemical Connections 13B) What is a...Ch. 13 - 13-40 (Chemical Connections 130 In the absence of...Ch. 13 - Prob. 13.41PCh. 13 - 13-42 (Chemical Connections 13E) What are the...Ch. 13 - 13-43 (Chemical Connections 13E) Which features of...Ch. 13 - 13-44 (Chemical Connections 13E) What color would...Ch. 13 - Prob. 13.45PCh. 13 - Prob. 13.46PCh. 13 - Prob. 13.47PCh. 13 - 13-48 (Chemical Connections 13F, How many...Ch. 13 - 13-49 (Chemical Connections 13F) In what ways is...Ch. 13 - 13*50 The structure for naphthalene given in...Ch. 13 - 13-51 Draw structural formulas for these...Ch. 13 - 13-52 2,6-Di-/ezY-butyl-4-methylphenol (BHT,...Ch. 13 - 13-53 Write the structural formula for the product...Ch. 13 - 13-54 Styrene reacts with bromine to give a...Ch. 13 - 13-55 When toluene is treated with Br, in the...Ch. 13 - 13-56 Four alternatives to the structure of...Ch. 13 - 13-57 Benzene, as we have seen in this chapter, is...
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