Please correct answer and don't use hand rating and don't use Ai solution CheckThe temperature on a sample of pure X held at 0.68 atm and -117. °C is increased until the sample boils. Thetemperature is then held constant and the pressure is decreased by 0.33 atm. On the phase diagram below draw a paththat shows this set of changes.?pressure (atm)100200temperature (K)300X5Save For LaterSubmit AssignmentAr00E

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Answered: Check The temperature on a sample of…

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter9: Liquids And Solids

Section: Chapter Questions

Problem 64QAP

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Why do liquids have a vapor pressure? Do all liquids have vapor pressures? Explain. Do solids exhibit vapor pressure? Explain. How does vapor pressure change with changing temperature? Explain.
8.87 Use the vapor pressure curves illustrated here to answer the questions that follow. (a) What is the vapor pressure of ethanol (C2H5OH) at 60°C? (b) Considering only carbon disulfide (CS2) and ethanol, which has the stranger intermolecular forces in the liquid state? (c) At what temperature does heptane (C7H16) have a vapor pressure of 500 mm Hg? (d) What are the approximate normal boiling pains of each of the three substances? (e) At a pressure of 400 mm Hg and a temperature of 70°C, is each substance a liquid, a gas, or a mixture of liquid and gas?
5-86 Using the phase diagram of water (Figure 5-20), describe the process by which you can sublime 1 g of ice at-10°C and at 1 atm pressure to water vapor at the same temperature.
Describe the behavior of a liquid and its vapor in a closed vessel as the temperature increases.
Chloroform, CHCl3, has a normal boiling point of 61C. Its vapor pressure at 43C is 0.526 atm. What is the concentration (in g/L) of CHCl3 when it saturates the air at 27C?
Referring to Figure 9.7, state what phase(s) is/are present at (a) 1 atm, 100C. (b) 0.5 atm, 100C.(c) 0.8 atm. 50C.
What phase changes will take place when water is subjected to varying pressure at a constant temperature of 0.005 C? At 40 C? At 40 C?
What are intermolecular forces? How do they differ from intramolecular forces? What are dipole-dipole forces? How do typical dipole-dipole forces differ from hydrogen bonding interactions? In what ways are they similar? What are London dispersion forces? How do typical London dispersion forces differ from dipole-dipole forces? In what ways are they similar? Describe the relationship between molecular size and strength of London dispersion forces. Place the major types of intermolecular forces in order of increasing strength. Is there some overlap? That is, can the strongest London dispersion forces be greater than some dipole-dipole forces? Give an example of such an instance.
Explain why evaporation leads to cooling of the liquid.
Two molecules that contain the same number of each kind of atom but [hat have different molecular structures are said to he isomers of each other. For example, both ethyl alcohol and dimethyl ether (shown below} have the formula C2H6Oand are isomers; Based on considerations of intermolecular forces. which substance would you expect to be more volatile? Which would you expect 10have the higher boiling point? Explain. methyl ether hyl alcohol msp;CH3OCH3CH3CH2OH
What feature characterizes the dynamic equilibrium between a liquid and its vapor in a closed container?
Consider a substance X with a Hvap = 20.3 kJ/mol and Hfus = 9.0 kJ/mol. The melting point, freezing point, and heat capacities of both the solid and liquid X are identical to those of water. a If you place one beaker containing 50 g of X at 10C and another beaker with 50 g of H2O at 10C on a hot plate and start heating them, which material will reach the boiling point first? b Which of the materials from part a, X or H2O, would completely boil away first? c On a piece of graph paper, draw the heating curve for H2O and X. How do the heating curves reflect your answers from parts a and b?

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