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Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 13, Problem 13.47P
Interpretation Introduction
Interpretation:
The phenol group in capsaicin should be identified.
Concept Introduction:
Capsaicin has an analgesic properties and it is an active ingredient in chili peppers. Molecular formula -
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In the Thermo Fisher application note about wine analysis (Lesson 3), the following
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MAU
300
200
T
34
5
100-
1 2
CO
6
7
8
9
0
2.4
2.6
2.8
3.0 3.2 3.4
3.6
3.8 4.0 4.2
4.4
4.6
4.8
5.0
5.2
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3.22
0.62
1.04
O 1.24
The diagram shows two
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1000°C
a+L
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12
α
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45
1200 C
L+y
140096
C+Y
a+ß
800°C
700°C
C+B
96
92
a+B
0
10
20
30
40
50
60
70 80 90 100
A
% peso B
B
8.
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2
4
3
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Chapter 13 Solutions
Introduction to General, Organic and Biochemistry
Ch. 13.2 - Prob. 13.1PCh. 13 - Answer true or false. Alkenes, alkynes, and arenes...Ch. 13 - 13-3 What is the difference in structure between a...Ch. 13 - 13-4 Define aromatic compound.Ch. 13 - 13-5 Why are alkenes, alkynes, and aromatic...Ch. 13 - 13-B Do aromatic rings have double bonds? Are they...Ch. 13 - 13-7 Can an aromatic compound be a saturated...Ch. 13 - Draw at least two structural formulas for each of...Ch. 13 - 13-9 Write a structural formula and the name for...Ch. 13 - 13-10 Account for the fact that the six-membered...
Ch. 13 - 13-11 Explain why the compound 1,4-dichlorobenzene...Ch. 13 - 13-12 One analogy often used to explain the...Ch. 13 - 13-13 Answer true or false. A phenyl group has the...Ch. 13 - Prob. 13.14PCh. 13 - 13-15 Draw structural formulas for these compounds...Ch. 13 - 13-16 We say that naphthalene, anthracene,...Ch. 13 - 13-17 Following is the structural formula of...Ch. 13 - 13-18 Answer true or false. Benzene does not...Ch. 13 - 13-19 Suppose you have unlabeled bottles of...Ch. 13 - 13-20 Three products with the molecular formula...Ch. 13 - 13-21 The reaction of bromine with toluene in the...Ch. 13 - 13-22 What reagents and/or catalysts are necessary...Ch. 13 - 13-23 What reagents and/or catalysts are necessary...Ch. 13 - Prob. 13.24PCh. 13 - 13-25 Answer true or false. (a) Phenols and...Ch. 13 - 13-26 Both phenol and cyclohexanol are only...Ch. 13 - 13-27 Define autoxidation.Ch. 13 - 13*28 Autoxidation is described as a radical-chain...Ch. 13 - 13-29 Show that if you add Steps 2a and 2b of the...Ch. 13 - 13-30 How does vitamin E function as an...Ch. 13 - 13-31 What structural features are common to...Ch. 13 - 13*32 Black-and-white photography is a commercial...Ch. 13 - 13-33 Following is the structural formula of...Ch. 13 - 13-34 (Chemical Connections 13A) From what parts...Ch. 13 - Prob. 13.35PCh. 13 - 13-36 (Chemical Connections 13A, Would you expect...Ch. 13 - Prob. 13.37PCh. 13 - 13-38 (Chemical Connections 13A) What is meant by...Ch. 13 - 13-39 (Chemical Connections 13B) What is a...Ch. 13 - 13-40 (Chemical Connections 130 In the absence of...Ch. 13 - Prob. 13.41PCh. 13 - 13-42 (Chemical Connections 13E) What are the...Ch. 13 - 13-43 (Chemical Connections 13E) Which features of...Ch. 13 - 13-44 (Chemical Connections 13E) What color would...Ch. 13 - Prob. 13.45PCh. 13 - Prob. 13.46PCh. 13 - Prob. 13.47PCh. 13 - 13-48 (Chemical Connections 13F, How many...Ch. 13 - 13-49 (Chemical Connections 13F) In what ways is...Ch. 13 - 13*50 The structure for naphthalene given in...Ch. 13 - 13-51 Draw structural formulas for these...Ch. 13 - 13-52 2,6-Di-/ezY-butyl-4-methylphenol (BHT,...Ch. 13 - 13-53 Write the structural formula for the product...Ch. 13 - 13-54 Styrene reacts with bromine to give a...Ch. 13 - 13-55 When toluene is treated with Br, in the...Ch. 13 - 13-56 Four alternatives to the structure of...Ch. 13 - 13-57 Benzene, as we have seen in this chapter, is...
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- 7. Assign all of the protons on the spectrum below. A B 2 C E 2 1 3 6 4 3 2 1 0arrow_forwarde. If (3R,4R)-3,4-dichloro-2,5-dimethylhexane and (3R,4S)-3,4-dichloro-2,5-dimethylhexane are in a solution at the same concentration, would this solution be expected to rotate plane polarized light (that is, be optically active)? Please provide your reasoning for your answer. [If you read this problem carefully, you will not need to draw out the structures to arrive at your answer...]arrow_forward1. How many neighbors does the proton that produces the multiplet below have? 2. 3. اللـ Draw a partial structure from the multiplet below. (The integration of the multiplet is 6) M Using the additivity constants found in appendix G of your lab manual, calculate the approximate chemical shifts of the protons indicated below. (Show your work!!!) B A Br SHarrow_forward
- 1) Suppose 0.1 kg ice at 0°C (273K) is in 0.5kg water at 20°C (293K). What is the change in entropy of the ice as it melts at 0°? To produce the original "water gas" mixture, carbon (in a combustible form known as coke) is reacted with steam: 131.4 kJ + H20(g) + C(s) → CO(g) + H2(g) From this information and the equations in the previous problem, calculate the enthalpy for the combustion or carbon to form carbon dioxide. kindly show me how to solve this long problem. Thanksarrow_forward4. An 'H-NMR of a compound is acquired. The integration for signal A is 5692 and the integration for signal B is 25614. What is the simplest whole number ratio of protons for signals A and B? (Show your work!!!) 5. Assign the carbons in the NMR below as either carbonyl, aromatic, or alkyl. 200 150 100 50 ō (ppm) 1arrow_forwardSpeaking of composite materials, indicate the correct option:(A). Composite materials can only be: metal-polymer or polymer-polymer.(B). Composite materials can be made up of particles, but not fibers or sheets.(C). When the reinforcing particles are uniformly distributed in a composite material, there may be a greater tendency for it to have isotropic properties.(D). None of the above is correct.arrow_forward
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