Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 13, Problem 13.29P
13-29 Show that if you add Steps 2a and 2b of the radical- chain mechanism for the autoxidation of a fatty acid hydrocarbon chain, you arrive at the following net equation:
H
I
—CH2CH=CH—CH— + 0—0 • »
Section of a fatty acid
Oxygen
hydrocarbon chain
O—O—H
I
—CH2CH=CH—CH—
A hydroperoxide
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Chapter 13 Solutions
Introduction to General, Organic and Biochemistry
Ch. 13.2 - Prob. 13.1PCh. 13 - Answer true or false. Alkenes, alkynes, and arenes...Ch. 13 - 13-3 What is the difference in structure between a...Ch. 13 - 13-4 Define aromatic compound.Ch. 13 - 13-5 Why are alkenes, alkynes, and aromatic...Ch. 13 - 13-B Do aromatic rings have double bonds? Are they...Ch. 13 - 13-7 Can an aromatic compound be a saturated...Ch. 13 - Draw at least two structural formulas for each of...Ch. 13 - 13-9 Write a structural formula and the name for...Ch. 13 - 13-10 Account for the fact that the six-membered...
Ch. 13 - 13-11 Explain why the compound 1,4-dichlorobenzene...Ch. 13 - 13-12 One analogy often used to explain the...Ch. 13 - 13-13 Answer true or false. A phenyl group has the...Ch. 13 - Prob. 13.14PCh. 13 - 13-15 Draw structural formulas for these compounds...Ch. 13 - 13-16 We say that naphthalene, anthracene,...Ch. 13 - 13-17 Following is the structural formula of...Ch. 13 - 13-18 Answer true or false. Benzene does not...Ch. 13 - 13-19 Suppose you have unlabeled bottles of...Ch. 13 - 13-20 Three products with the molecular formula...Ch. 13 - 13-21 The reaction of bromine with toluene in the...Ch. 13 - 13-22 What reagents and/or catalysts are necessary...Ch. 13 - 13-23 What reagents and/or catalysts are necessary...Ch. 13 - Prob. 13.24PCh. 13 - 13-25 Answer true or false. (a) Phenols and...Ch. 13 - 13-26 Both phenol and cyclohexanol are only...Ch. 13 - 13-27 Define autoxidation.Ch. 13 - 13*28 Autoxidation is described as a radical-chain...Ch. 13 - 13-29 Show that if you add Steps 2a and 2b of the...Ch. 13 - 13-30 How does vitamin E function as an...Ch. 13 - 13-31 What structural features are common to...Ch. 13 - 13*32 Black-and-white photography is a commercial...Ch. 13 - 13-33 Following is the structural formula of...Ch. 13 - 13-34 (Chemical Connections 13A) From what parts...Ch. 13 - Prob. 13.35PCh. 13 - 13-36 (Chemical Connections 13A, Would you expect...Ch. 13 - Prob. 13.37PCh. 13 - 13-38 (Chemical Connections 13A) What is meant by...Ch. 13 - 13-39 (Chemical Connections 13B) What is a...Ch. 13 - 13-40 (Chemical Connections 130 In the absence of...Ch. 13 - Prob. 13.41PCh. 13 - 13-42 (Chemical Connections 13E) What are the...Ch. 13 - 13-43 (Chemical Connections 13E) Which features of...Ch. 13 - 13-44 (Chemical Connections 13E) What color would...Ch. 13 - Prob. 13.45PCh. 13 - Prob. 13.46PCh. 13 - Prob. 13.47PCh. 13 - 13-48 (Chemical Connections 13F, How many...Ch. 13 - 13-49 (Chemical Connections 13F) In what ways is...Ch. 13 - 13*50 The structure for naphthalene given in...Ch. 13 - 13-51 Draw structural formulas for these...Ch. 13 - 13-52 2,6-Di-/ezY-butyl-4-methylphenol (BHT,...Ch. 13 - 13-53 Write the structural formula for the product...Ch. 13 - 13-54 Styrene reacts with bromine to give a...Ch. 13 - 13-55 When toluene is treated with Br, in the...Ch. 13 - 13-56 Four alternatives to the structure of...Ch. 13 - 13-57 Benzene, as we have seen in this chapter, is...
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