General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 13, Problem 13.135QP
A possible mechanism for a gas-phase reaction is given below. What is the rate law predicted by this mechanism?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Chapter 13 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 13.1 - For the reaction given in Example 13.1, how is the...Ch. 13.1 - Iodide ion is oxidized by hypochlorite ion in...Ch. 13.1 - Shown here is a plot of the concentration of a...Ch. 13.3 - Prob. 13.3ECh. 13.3 - Prob. 13.2CCCh. 13.3 - Prob. 13.4ECh. 13.3 - Prob. 13.3CCCh. 13.4 - a. What would be the concentration of dinitrogen...Ch. 13.4 - The isomerization of cyclopropane, C3H6, to...Ch. 13.4 - A reaction believed to be either first or second...
Ch. 13.5 - Consider the following potential-energy curves for...Ch. 13.6 - Acetaldehyde, CH3CHO, decomposes when heated....Ch. 13.7 - Prob. 13.8ECh. 13.7 - Prob. 13.9ECh. 13.7 - Prob. 13.10ECh. 13.8 - The iodide-ion-catalyzed decomposition of hydrogen...Ch. 13.8 - Prob. 13.12ECh. 13.8 - Prob. 13.6CCCh. 13 - List the four variables or factors that can affect...Ch. 13 - Define the rate of reaction of HBr in the...Ch. 13 - Give at least two physical properties that might...Ch. 13 - A rate of reaction depends on four variables...Ch. 13 - Prob. 13.5QPCh. 13 - The reaction...Ch. 13 - The rate of a reaction is quadrupled when the...Ch. 13 - Prob. 13.8QPCh. 13 - The reaction A(g)B(g)+C(g) is known to be first...Ch. 13 - Prob. 13.10QPCh. 13 - Prob. 13.11QPCh. 13 - Sketch a potential-energy diagram for the...Ch. 13 - Draw a structural formula for the activated...Ch. 13 - Prob. 13.14QPCh. 13 - Prob. 13.15QPCh. 13 - Prob. 13.16QPCh. 13 - Prob. 13.17QPCh. 13 - Prob. 13.18QPCh. 13 - The dissociation of N2O4 into NO2, N2O4(g)2NO2(g)...Ch. 13 - Prob. 13.20QPCh. 13 - Prob. 13.21QPCh. 13 - Prob. 13.22QPCh. 13 - You are running the reaction 2A+BC+3D. Your lab...Ch. 13 - At a constant temperature, which of the following...Ch. 13 - Consider the reaction E+FG+H, which has the...Ch. 13 - The hypothetical reaction A+B+CD+E has the rate...Ch. 13 - Kinetics I Consider the hypothetical reaction A(g)...Ch. 13 - Kinetics II You and a friend are working together...Ch. 13 - Consider the reaction 3A2B+C. a One rate...Ch. 13 - Given the reaction 2A+BC+3D, can you write the...Ch. 13 - The reaction 2A(g)A2(g) is being run in each of...Ch. 13 - Prob. 13.32QPCh. 13 - You perform some experiments for the reaction AB+C...Ch. 13 - A friend of yours runs a reaction and generates...Ch. 13 - Prob. 13.35QPCh. 13 - You carry out the following reaction by...Ch. 13 - Prob. 13.37QPCh. 13 - The chemical reaction AB+C has a rate constant...Ch. 13 - Relate the rate of decomposition of NH4NO2 to the...Ch. 13 - For the reaction of hydrogen with iodine...Ch. 13 - To obtain the rate of the reaction...Ch. 13 - To obtain the rate of the reaction...Ch. 13 - Ammonium nitrite, NH4NO2, decomposes in solution,...Ch. 13 - Iron(III) chloride is reduced by tin(II) chloride....Ch. 13 - Azomethane, CH3NNCH3, decomposes according to the...Ch. 13 - Nitrogen dioxide, NO2, decomposes upon heating to...Ch. 13 - Hydrogen sulfide is oxidized by chlorine in...Ch. 13 - For the reaction of nitrogen monoxide, NO, with...Ch. 13 - Prob. 13.49QPCh. 13 - Prob. 13.50QPCh. 13 - In experiments on the decomposition of azomethane....Ch. 13 - Ethylene oxide. C2H4O, decomposes when heated to...Ch. 13 - Nitrogen monoxide NO, reacts with hydrogen to give...Ch. 13 - In a kinetic study of the reaction...Ch. 13 - Chlorine dioxide, ClO2, is a reddish-yellow gas...Ch. 13 - Iodide ion is oxidized to hypoiodite ion, IO, by...Ch. 13 - Sulfuryl chloride, SO2Cl2, decomposes when heated....Ch. 13 - Cyclopropane, C3H6, is converted to its isomer...Ch. 13 - A reaction of the form aA Products is second-order...Ch. 13 - A reaction of the form aA Products is second order...Ch. 13 - Ethyl chloride, CH3CH2Cl, used to produce...Ch. 13 - Cyclobutane, C4H8, consisting of molecules in...Ch. 13 - Methyl isocyanide, CH3NC, isomerizes, when heated,...Ch. 13 - Dinitrogen pentoxide, N2O5, decomposes when heated...Ch. 13 - In the presence of excess thiocyanate ion, SCN,...Ch. 13 - In the presence of excess thiocyanate ion, SCN,...Ch. 13 - A reaction of the form aA Products is second order...Ch. 13 - A reaction of the form aA Products is second order...Ch. 13 - In the presence of excess thiocyanate ion, SCN,...Ch. 13 - In the presence of excess thiocyanate ion, SCN,...Ch. 13 - It is found that a gas undergoes a zero-order...Ch. 13 - The reaction AB+C is found to be zero order. If it...Ch. 13 - Chlorine dioxide oxidizes iodide ion in aqueous...Ch. 13 - Methyl acetate, CH3COOCH3, reacts in basic...Ch. 13 - Sketch a potential-energy diagram for the reaction...Ch. 13 - Sketch a potential-energy diagram for the...Ch. 13 - In a series of experiments on the decomposition of...Ch. 13 - The reaction 2NOCl(g)2NO(g)+Cl2(g) has...Ch. 13 - The rate of a particular reaction increases by a...Ch. 13 - The rate of a particular reaction quadruples when...Ch. 13 - The following values of the rate constant were...Ch. 13 - The following values of the rate constant were...Ch. 13 - Nitrogen monoxide, NO, is believed to react with...Ch. 13 - The decomposition of ozone is believed to occur in...Ch. 13 - Identify the molecularity of each of the following...Ch. 13 - Prob. 13.86QPCh. 13 - Write a rate equation, showing the dependence of...Ch. 13 - Prob. 13.88QPCh. 13 - The isomerization of cyclopropane, C3H6, is...Ch. 13 - The thermal decomposition of nitryl chloride,...Ch. 13 - The reaction H2(g)+I2(g)2HI(g) may occur by the...Ch. 13 - Ozone decomposes to oxygen gas. 2O3(g)3O2(g) A...Ch. 13 - The following is a possible mechanism for a...Ch. 13 - Consider the following mechanism for a reaction in...Ch. 13 - A study of the decomposition of azomethane,...Ch. 13 - Nitrogen dioxide decomposes when heated....Ch. 13 - Prob. 13.97QPCh. 13 - Prob. 13.98QPCh. 13 - Methyl acetate reacts in acidic solution....Ch. 13 - Benzene diazonium chloride, C6H5NNCl, decomposes...Ch. 13 - What is the half-life of methyl acetate hydrolysis...Ch. 13 - What is the half-life of benzene diazonium...Ch. 13 - A compound decomposes by a first-order reaction....Ch. 13 - A compound decomposes by a first-order reaction....Ch. 13 - Butadiene can undergo the following reaction to...Ch. 13 - Prob. 13.106QPCh. 13 - Prob. 13.107QPCh. 13 - A second-order decomposition reaction run at 550oC...Ch. 13 - Prob. 13.109QPCh. 13 - Prob. 13.110QPCh. 13 - Prob. 13.111QPCh. 13 - Prob. 13.112QPCh. 13 - The decomposition of nitrogen dioxide,...Ch. 13 - Prob. 13.114QPCh. 13 - Prob. 13.115QPCh. 13 - Prob. 13.116QPCh. 13 - Nitryl bromide, NO2Br, decomposes into nitrogen...Ch. 13 - Tertiary butyl chloride reacts in basic solution...Ch. 13 - Urea, (NH2)2CO, can be prepared by heating...Ch. 13 - Prob. 13.120QPCh. 13 - A study of the gas-phase oxidation of nitrogen...Ch. 13 - The reaction of water with CH3Cl in acetone as a...Ch. 13 - The reaction of thioacelamidc with water is shown...Ch. 13 - Prob. 13.124QPCh. 13 - Prob. 13.125QPCh. 13 - Prob. 13.126QPCh. 13 - Prob. 13.127QPCh. 13 - Prob. 13.128QPCh. 13 - Prob. 13.129QPCh. 13 - Prob. 13.130QPCh. 13 - The rate constant for a certain reaction is 1.4 ...Ch. 13 - The decomposition of hydrogen peroxide is a first...Ch. 13 - Prob. 13.133QPCh. 13 - What is the rate law for the following gas-phase...Ch. 13 - A possible mechanism for a gas-phase reaction is...Ch. 13 - Say you run the following elementary, termolecular...Ch. 13 - Prob. 13.137QPCh. 13 - For the decomposition of one mole of nitrosyl...Ch. 13 - Given the following mechanism for a chemical...Ch. 13 - The following data were collected for the reaction...Ch. 13 - A hypothetical reaction has the two-step mechanism...Ch. 13 - Prob. 13.142QPCh. 13 - Prob. 13.143QPCh. 13 - Prob. 13.144QPCh. 13 - Dinitrogen pentoxide decomposes according to the...Ch. 13 - Prob. 13.146QPCh. 13 - Dinitrogen pentoxide, N2O5, undergoes first-order...Ch. 13 - Prob. 13.148QPCh. 13 - Hydrogen peroxide in aqueous solution decomposes...Ch. 13 - Nitrogen dioxide reacts with carbon monoxide by...Ch. 13 - Nitrogen monoxide reacts with oxygen to give...Ch. 13 - Nitrogen monoxide reacts with hydrogen as follows:...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The ozone in the Earths ozone layer decomposes according to the equation 2 O3(g) 3 O2(g) The mechanism of the reaction is thought to proceed through an initial fast equilibrium and a slow step: Show that the mechanism agrees with this experimental rate law: Rate = (1/2)[O3]/t = k[O3]2[O2].arrow_forwardThe Raschig reaction produces the industrially important reducing agent hydrazine, N2H4, from ammonia, NH3, and hypochlorite ion, OCl−, in basic aqueous solution. A proposed mechanism is Step 1: Step 2: Step 3: What is the overall stoichiometric equation? Which step is rate-limiting? What reaction intermediates are involved? What rate law is predicted by this mechanism?arrow_forwardConsider the reaction of ozone and nitrogen monoxide to form nitrogen dioxide and oxygen. O3(g) + NO(g) NO2(g) + O2(g) Which of the following orientations for the collision between ozone and nitrogen monoxide could perhaps lead to an effective collision between the molecules? (a) (b) (c) (d)arrow_forward
- The following statements relate to the reaction for the formation of HI: H2(g) + I2(g) 2 HI(g)Rate = k[H2][I2] Determine which of the following statements are true. If a statement is false, indicate why it is incorrect. (a) The reaction must occur in a single step. (b) This is a second-order reaction overall. (c) Raising the temperature will cause the value of k to decrease. (d) Raising the temperature lowers the activation energy for this reaction. (e) If the concentrations of both reactants are doubled, the rate will double. (f) Adding a catalyst in the reaction will cause the initial rate to increase.arrow_forwardThe rate constant, k, at 25 C is 0.27/h for the reaction Pt(NH3)2Cl2(aq) + H2O() [Pt(NH3)2(H2O)Cl]+(aq) + Cl(aq) and the rate equation is Reaction rate = k[Pt(NH3)2C12] Calculate the rate of reaction when the concentration of Pt(NH3)2Cl2 is 0.020 M.arrow_forwardNitrogen monoxide reacts with hydrogen as follows: 2NO(g)+H2(g)N2O(g)+H2O(g) The rate law is [H2]/t = k[NO]2[H2], where k is 1.10 107 L2/(mol2 s) at 826C. A vessel contains NO and H2 at 826C. The partial pressures of NO and H2 are 144 mmHg and 315 mmHg, respectively. What is the rate of decrease of partial pressure of NO? See Problem 13.151.arrow_forward
- Consider the following statements: In general, the rate of a chemical reaction increases a bit at first because it takes a while for the reaction to get warmed up. After that, however, the rate of the reaction decreases because its rate is dependent on the concentrations of the reactants, and these are decreasing. Indicate everything that is correct in these statements, and indicate everything that is incorrect. Correct the incorrect statements and explain.arrow_forward(Section 11-5) A rule of thumb is that for a typical reaction, if concentrations are unchanged, a 10-K rise in temperature increases the reaction rate by two to four times. Use an average increase of three times to answer the questions below. (a) What is the approximate activation energy of a typical chemical reaction at 298 K? (b) If a catalyst increases a chemical reactions rate by providing a mechanism that has a lower activation energy, then what change do you expect a 10-K increase in temperature to make in the rate of a reaction whose uncatalyzed activation energy of 75 kJ/mol has been lowered to one half this value (at 298 K) by addition of a catalyst?arrow_forwardThe following statements relate to the reaction for the formation of HI: H2(g) + I2(g) -* 2 HI(g) Rate = it[HJ [I2J Determine which of the following statements are true. If a statement is false, indicate why it is incorrect. The reaction must occur in a single step. This is a second-order reaction overall. Raising the temperature will cause the value of k to decrease. Raising the temperature lowers the activation energy' for this reaction. If the concentrations of both reactants are doubled, the rate will double. Adding a catalyst in the reaction will cause the initial rate to increase.arrow_forward
- The reaction H2SeO3(aq) + 6I-(aq) + 4H+(aq) Se(s) + 2I-3(aq) + 3H2O(l) was studied at 0C, and the following data were obtained: [H2SeO3]0 (mol/L) [H+]0 (mol/L) [I]0(mol/L) Initial Rate (mol/L s) 1.0 104 2.0 102 2.0 102 1.66 107 2.0 104 2.0 102 2.0 10-2 3.33 107 3.0 104 2.0 102 2.0 102 4.99 107 1.0 104 4.0 102 2.0 102 6.66 107 1.0 104 1.0 102 2.0 102 0.42 107 1.0 104 2.0 102 4.0 102 13.2 107 1.0 104 1.0 102 4.0 102 3.36 107 These relationships hold only if there is a very small amount of I3 present. What is the rate law and the value of the rate constant? (Assumethatrate=[H2SeO3]t)arrow_forwardThe reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in automobile engines. Suppose that a series of experiments measured the rate of this reaction at 500 K and produced the following data; [NO] (mol L ’) [OJ (mol L 1) Rate = -A[NO]/Af (mol L_1 s-1) 0.002 0.005 8.0 X 10"'7 0.002 0.010 1.6 X 10-'6 0.006 0.005 2.4 X IO-'6 Derive a rate law for the reaction and determine the value of the rate constant.arrow_forwardWrite a rate law for NO3(g) + O2(g) NO2(g) + O3(g) if measurements show the reaction is first order in nitrogen trioxide and second order in oxygen.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY