The explanation has to be given why the mechanism for the given reaction can’t be single elementary reaction. Concept Introduction: The rate of reaction is the quantity of formation of product or the quantity of reactant used per unit time. The rate of reaction doesn’t depend on the sum of amount of reaction mixture used. The raise in molar concentration of product of a reaction per unit time or decrease in molarity of reactant per unit time is called rate of reaction and is expressed in units of mol/(L .s) . The equation that relates the reaction rate to the reactants concentrations that is raised to various powers is called as rate law. To explain the reason why the mechanism for the given reaction can’t be single elementary reaction
The explanation has to be given why the mechanism for the given reaction can’t be single elementary reaction. Concept Introduction: The rate of reaction is the quantity of formation of product or the quantity of reactant used per unit time. The rate of reaction doesn’t depend on the sum of amount of reaction mixture used. The raise in molar concentration of product of a reaction per unit time or decrease in molarity of reactant per unit time is called rate of reaction and is expressed in units of mol/(L .s) . The equation that relates the reaction rate to the reactants concentrations that is raised to various powers is called as rate law. To explain the reason why the mechanism for the given reaction can’t be single elementary reaction
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Definition Definition Transformation of a chemical species into another chemical species. A chemical reaction consists of breaking existing bonds and forming new ones by changing the position of electrons. These reactions are best explained using a chemical equation.
Chapter 13, Problem 13.17QP
Interpretation Introduction
Interpretation:
The explanation has to be given why the mechanism for the given reaction can’t be single elementary reaction.
Concept Introduction:
The rate of reaction is the quantity of formation of product or the quantity of reactant used per unit time. The rate of reaction doesn’t depend on the sum of amount of reaction mixture used.
The raise in molar concentration of product of a reaction per unit time or decrease in molarity of reactant per unit time is called rate of reaction and is expressed in units of mol/(L.s).
The equation that relates the reaction rate to the reactants concentrations that is raised to various powers is called as rate law.
To explain the reason why the mechanism for the given reaction can’t be single elementary reaction
Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 13 Solutions
General Chemistry - Standalone book (MindTap Course List)
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