Concept explainers
(a)
Interpretation: To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.
Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.
Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.
(b)
Interpretation: To identify the compound among creatine phosphate and ADP that releases more energy upon hydrolysis.
Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.
Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.
(c)
Interpretation: To identify the compound among
Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.
Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.
(d)
Interpretation: To identify the compound among AMP and
Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.
Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.
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Chapter 12 Solutions
Organic And Biological Chemistry
- Add curved arrows to the reactants in this reaction. A double-barbed curved arrow is used to represent the movement of a pair of electrons. Draw curved arrows. : 0: si H : OH :: H―0: Harrow_forwardConsider this step in a radical reaction: Br N O hv What type of step is this? Check all that apply. Draw the products of the step on the right-hand side of the drawing area below. If more than one set of products is possible, draw any set. Also, draw the mechanism arrows on the left-hand side of the drawing area to show how this happens. O primary Otermination O initialization O electrophilic O none of the above × ☑arrow_forwardNonearrow_forward
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- Is this aromatic?arrow_forwardCHEM2323 E Tt PS CH03 Draw and name all monobromo derivatives of pentane, C5H11Br. Problem 3-33 Name: Draw structures for the following: (a) 2-Methylheptane (d) 2,4,4-Trimethylheptane Problem 3-35 (b) 4-Ethyl-2,2-dimethylhexane (e) 3,3-Diethyl-2,5-dimethylnonane (c) 4-Ethyl-3,4-dimethyloctane 2 (f) 4-Isopropyl-3-methylheptane KNIE>arrow_forwardProblem 3-42 Consider 2-methylbutane (isopentane). Sighting along the C2-C3 bond: (a) Draw a Newman projection of the most stable conformation. (b) Draw a Newman projection of the least stable conformation. Problem 3-44 Construct a qualitative potential-energy diagram for rotation about the C-C bond of 1,2-dibromoethane. Which conformation would you expect to be most stable? Label the anti and gauche conformations of 1,2- dibromoethane. Problem 3-45 Which conformation of 1,2-dibromoethane (Problem 3-44) would you expect to have the largest dipole moment? The observed dipole moment of 1,2-dibromoethane is µ = 1.0 D. What does this tell you about the actual conformation of the molecule?arrow_forward
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