Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 12, Problem 12.104QE
A 10.00-mL sample of a 24.00% solution of ammonium bromide (NH4Br) requires 23.41 mL of 1.200 molar silver nitrate (AgNO3) to react with all of the bromide ion present.
- (a) Calculate the molarity of the ammonium bromide solution.
- (b) Use the molarity of the solution to find the mass of ammonium bromide in 1.000 L of this solution.
- (c) From the percentage concentration and the answer to part b, find the mass of 1.000 L ammonium bromide solution.
- (d) Combine the answer to part c with the volume of 1.000 L to express the density of the ammonium bromide solution (in g/mL).
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 12 Solutions
Chemistry: Principles and Practice
Ch. 12 - Prob. 12.1QECh. 12 - Prob. 12.2QECh. 12 - Prob. 12.3QECh. 12 - Prob. 12.4QECh. 12 - Prob. 12.5QECh. 12 - Prob. 12.6QECh. 12 - Prob. 12.7QECh. 12 - Prob. 12.8QECh. 12 - Prob. 12.9QECh. 12 - Prob. 12.10QE
Ch. 12 - Prob. 12.11QECh. 12 - Prob. 12.12QECh. 12 - Create a flow diagram, similar to those used in...Ch. 12 - Prob. 12.14QECh. 12 - Prob. 12.15QECh. 12 - Prob. 12.16QECh. 12 - Prob. 12.17QECh. 12 - Prob. 12.18QECh. 12 - Prob. 12.19QECh. 12 - Prob. 12.20QECh. 12 - Prob. 12.21QECh. 12 - Prob. 12.22QECh. 12 - Prob. 12.23QECh. 12 - Prob. 12.24QECh. 12 - Prob. 12.25QECh. 12 - Prob. 12.26QECh. 12 - Prob. 12.27QECh. 12 - What is the molality of copper(II) bromide (CuBr2)...Ch. 12 - Prob. 12.29QECh. 12 - Prob. 12.30QECh. 12 - A water solution of sodium hypochlorite (NaOCl) is...Ch. 12 - Prob. 12.32QECh. 12 - Prob. 12.33QECh. 12 - Vinegar is a 5.0% solution of acetic acid...Ch. 12 - Prob. 12.35QECh. 12 - A 2.77 M NaOH solution in water has a density of...Ch. 12 - The density of a 3.75 M aqueous sulfuric acid...Ch. 12 - Prob. 12.40QECh. 12 - Prob. 12.41QECh. 12 - Prob. 12.42QECh. 12 - Predict the relative solubility of each compound...Ch. 12 - Predict the relative solubility of each compound...Ch. 12 - Prob. 12.45QECh. 12 - Prob. 12.46QECh. 12 - Prob. 12.47QECh. 12 - Prob. 12.48QECh. 12 - Prob. 12.49QECh. 12 - The solubility of ethylene (C2H4) in water at 20 C...Ch. 12 - Prob. 12.51QECh. 12 - Prob. 12.52QECh. 12 - Prob. 12.53QECh. 12 - Prob. 12.54QECh. 12 - Prob. 12.55QECh. 12 - Prob. 12.56QECh. 12 - From the data presented in Figure 12.11, determine...Ch. 12 - Prob. 12.58QECh. 12 - Prob. 12.59QECh. 12 - Prob. 12.60QECh. 12 - Prob. 12.61QECh. 12 - Prob. 12.62QECh. 12 - The vapor pressure of chloroform (CHCl3) is 360...Ch. 12 - Prob. 12.64QECh. 12 - Prob. 12.65QECh. 12 - Prob. 12.66QECh. 12 - Prob. 12.67QECh. 12 - Prob. 12.68QECh. 12 - Prob. 12.69QECh. 12 - Prob. 12.70QECh. 12 - A solution of 1.00 g of a protein in 20.0 mL water...Ch. 12 - Prob. 12.72QECh. 12 - Arrange the following aqueous solutions in order...Ch. 12 - Arrange the following solutions in order of...Ch. 12 - Prob. 12.75QECh. 12 - An aqueous solution of sodium bromide freezes at...Ch. 12 - Prob. 12.77QECh. 12 - Prob. 12.78QECh. 12 - Prob. 12.79QECh. 12 - Prob. 12.80QECh. 12 - A 0.029 M solution of potassium sulfate has an...Ch. 12 - The freezing point of a 0.031-m solution of...Ch. 12 - Prob. 12.83QECh. 12 - Prob. 12.84QECh. 12 - Prob. 12.85QECh. 12 - Prob. 12.86QECh. 12 - Prob. 12.87QECh. 12 - Prob. 12.88QECh. 12 - Prob. 12.89QECh. 12 - Prob. 12.90QECh. 12 - Predict the relative solubility of each compound...Ch. 12 - Prob. 12.92QECh. 12 - Prob. 12.94QECh. 12 - Prob. 12.95QECh. 12 - Prob. 12.96QECh. 12 - Sketch graphs of total vapor pressure versus the...Ch. 12 - Prob. 12.98QECh. 12 - Prob. 12.99QECh. 12 - Prob. 12.100QECh. 12 - Prob. 12.101QECh. 12 - Prob. 12.102QECh. 12 - Prob. 12.103QECh. 12 - A 10.00-mL sample of a 24.00% solution of ammonium...Ch. 12 - Prob. 12.105QECh. 12 - In the 1986 Lake Nyos disaster (see the chapter...Ch. 12 - Prob. 12.107QE
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY