Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 12, Problem 12.7QE
Interpretation Introduction
Interpretation:
The solubility of straight chain alcohols in water based on the value of
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(b) How do the structures of these molecules account for these differences
in solubility? Provide a full account of the structures and their influence
on intermolecular forces that might account for the differences in this
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Name
Solubility 20
1-butanol
73 g/L
butanal
7.6 g/100 mL
butanone
27.5 g/100 mL
1-chlorobutane
0.5 g/L
*00
B-Galactosidase (B-gal) is a hydrolase enzyme that catalyzes the hydrolysis of B-galactosides into monosaccharides. A 0.607 g
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Question Source: McQuarrie, Rock, And Gallogly 4e - General Chemsitry Publisher: University Science Books
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Consider a body of water in equilibrium with solid calcium sulfate, CaSO4, for which Ksp = 3.0 * 10^-5 at 35 degrees C. Calculate the solubility, in g/L of calcium sulfate in water assuming that other reactions are negligible.
Chapter 12 Solutions
Chemistry: Principles and Practice
Ch. 12 - Prob. 12.1QECh. 12 - Prob. 12.2QECh. 12 - Prob. 12.3QECh. 12 - Prob. 12.4QECh. 12 - Prob. 12.5QECh. 12 - Prob. 12.6QECh. 12 - Prob. 12.7QECh. 12 - Prob. 12.8QECh. 12 - Prob. 12.9QECh. 12 - Prob. 12.10QE
Ch. 12 - Prob. 12.11QECh. 12 - Prob. 12.12QECh. 12 - Create a flow diagram, similar to those used in...Ch. 12 - Prob. 12.14QECh. 12 - Prob. 12.15QECh. 12 - Prob. 12.16QECh. 12 - Prob. 12.17QECh. 12 - Prob. 12.18QECh. 12 - Prob. 12.19QECh. 12 - Prob. 12.20QECh. 12 - Prob. 12.21QECh. 12 - Prob. 12.22QECh. 12 - Prob. 12.23QECh. 12 - Prob. 12.24QECh. 12 - Prob. 12.25QECh. 12 - Prob. 12.26QECh. 12 - Prob. 12.27QECh. 12 - What is the molality of copper(II) bromide (CuBr2)...Ch. 12 - Prob. 12.29QECh. 12 - Prob. 12.30QECh. 12 - A water solution of sodium hypochlorite (NaOCl) is...Ch. 12 - Prob. 12.32QECh. 12 - Prob. 12.33QECh. 12 - Vinegar is a 5.0% solution of acetic acid...Ch. 12 - Prob. 12.35QECh. 12 - A 2.77 M NaOH solution in water has a density of...Ch. 12 - The density of a 3.75 M aqueous sulfuric acid...Ch. 12 - Prob. 12.40QECh. 12 - Prob. 12.41QECh. 12 - Prob. 12.42QECh. 12 - Predict the relative solubility of each compound...Ch. 12 - Predict the relative solubility of each compound...Ch. 12 - Prob. 12.45QECh. 12 - Prob. 12.46QECh. 12 - Prob. 12.47QECh. 12 - Prob. 12.48QECh. 12 - Prob. 12.49QECh. 12 - The solubility of ethylene (C2H4) in water at 20 C...Ch. 12 - Prob. 12.51QECh. 12 - Prob. 12.52QECh. 12 - Prob. 12.53QECh. 12 - Prob. 12.54QECh. 12 - Prob. 12.55QECh. 12 - Prob. 12.56QECh. 12 - From the data presented in Figure 12.11, determine...Ch. 12 - Prob. 12.58QECh. 12 - Prob. 12.59QECh. 12 - Prob. 12.60QECh. 12 - Prob. 12.61QECh. 12 - Prob. 12.62QECh. 12 - The vapor pressure of chloroform (CHCl3) is 360...Ch. 12 - Prob. 12.64QECh. 12 - Prob. 12.65QECh. 12 - Prob. 12.66QECh. 12 - Prob. 12.67QECh. 12 - Prob. 12.68QECh. 12 - Prob. 12.69QECh. 12 - Prob. 12.70QECh. 12 - A solution of 1.00 g of a protein in 20.0 mL water...Ch. 12 - Prob. 12.72QECh. 12 - Arrange the following aqueous solutions in order...Ch. 12 - Arrange the following solutions in order of...Ch. 12 - Prob. 12.75QECh. 12 - An aqueous solution of sodium bromide freezes at...Ch. 12 - Prob. 12.77QECh. 12 - Prob. 12.78QECh. 12 - Prob. 12.79QECh. 12 - Prob. 12.80QECh. 12 - A 0.029 M solution of potassium sulfate has an...Ch. 12 - The freezing point of a 0.031-m solution of...Ch. 12 - Prob. 12.83QECh. 12 - Prob. 12.84QECh. 12 - Prob. 12.85QECh. 12 - Prob. 12.86QECh. 12 - Prob. 12.87QECh. 12 - Prob. 12.88QECh. 12 - Prob. 12.89QECh. 12 - Prob. 12.90QECh. 12 - Predict the relative solubility of each compound...Ch. 12 - Prob. 12.92QECh. 12 - Prob. 12.94QECh. 12 - Prob. 12.95QECh. 12 - Prob. 12.96QECh. 12 - Sketch graphs of total vapor pressure versus the...Ch. 12 - Prob. 12.98QECh. 12 - Prob. 12.99QECh. 12 - Prob. 12.100QECh. 12 - Prob. 12.101QECh. 12 - Prob. 12.102QECh. 12 - Prob. 12.103QECh. 12 - A 10.00-mL sample of a 24.00% solution of ammonium...Ch. 12 - Prob. 12.105QECh. 12 - In the 1986 Lake Nyos disaster (see the chapter...Ch. 12 - Prob. 12.107QE
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- Simple acids such as formic acid, HCOOH, and acetic acid, CH3COOH, are very soluble in water; however, fatty acids such as stearic acid, CH3(CH2)16COOH, and palmitic acid, CH3(CH2)14COOH, are water-insoluble. Based on what you know about the solubility of alcohols, explain the solubility of these organic acids.arrow_forwardFor each of the following pairs of solutions, select the solution for which solute solubility is greatest. a. Ammonia gas in water with P = 1 atm and T = 50C Ammonia gas in water with P = 1 atm and T = 90C b. Carbon dioxide gas in water with P = 2 atm and T = 50C Carbon dioxide gas in water with P = 1 atm and T = 50C c. Table salt in water with P = 1 atm and T = 60C Table salt in water with P = 1 atm and T = 50C d. Table sugar in water with P = 2 atm and T = 40C Table sugar in water with P = 1 atm and T = 70Carrow_forwardCalculate the molality of a solution made by dissolving 115.0 g ethylene glycol, HOCH2CH2OH, in 500. mL water. The density of water at this temperature is 0.978 g/mL. Calculate the molarity of the solution.arrow_forward
- For each of the following pairs of solutions, select the solution for which solute solubility is greatest. a. Oxygen gas in water with P = 1 atm and T = 10C Oxygen gas in water with P = 1 atm and T = 20C b. Nitrogen gas in water with P = 2 atm and T = 50C Nitrogen gas in water with P = 1 atm and T = 70C c. Table salt in water with P = 1 atm and T = 40C Table salt in water with P = 1 atm and T = 70C d. Table sugar in water with P = 3 atm and T = 30C Table sugar in water with P = 1 atm and T = 80Carrow_forwardFluoridation of city water supplies has been practiced in the United States for several decades. It is done by continuously adding sodium fluoride to water as it comes from a reservoir. Assume you live in a medium-sized city of 150,000 people and that 660 L (170 gal) of water is used per person per day. What mass of sodium fluoride (in kilograms) must be added to the water supply each year (365 days) to have the required fluoride concentration of 1 ppm (part per million)that is, 1 kilogram of fluoride per 1 million kilograms of water? (Sodium fluoride is 45.0% fluoride, and water has a density of 1.00 g/cm3.)arrow_forwardA 0.109 mol/kg aqueous solution of formic acid, HCOOH, freezes at −0.210 °C. Calculate the percent dissociation of formic acid.arrow_forward
- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forwardPredict the relative solubility of each compound in the two solvents, on the basis of intermolecular attractions. (a) Is Br2 more soluble in water or in carbon tetrachloride? (b) Is CaCl2 more soluble in water or in benzene (C6H6)? (c) Is chloroform (CHCl3) more soluble in water or in diethyl ether [(C2H5)2O]? (d) Is ethylene glycol (HOCH2CH2OH) more soluble in water or in benzene (C6H6)?arrow_forwardThe freezing point of a 0.21 m aqueous solution of H2SO4 is -0.796C. (a) What is i? (b) Is the solution made up primarily of (i) H2SO4 molecules only? (ii) H+ and HSO4- ions? (iii) 2H+ and 1SO42- ions?arrow_forward
- Predict the relative solubility of each compound in the two solvents, based on the intermolecular attractions. (a) Is potassium iodide more soluble in water or in methylene chloride (CH2Cl2)? (b) Is toluene (C6H5CH3) more soluble in benzene (C6H6) or in water? (c) Is ethylene glycol (C2H4(OH)2) more soluble in hexane (C6H14) or in ethanol (C2H5OH)?arrow_forwardIn a mountainous location, the boiling point of pure water is found to be 95C. How many grams of sodium chloride must be added to 1 kg of water to bring the boiling point back to 100C? Assume that i = 2.arrow_forwardRefer to Figure 13.10 ( Sec. 13-4b) to answer these questions. (a) Does a saturated solution occur when 65.0 g LiCl is present in 100 g H2O at 40 C? Explain your answer. (b) Consider a solution that contains 95.0 g LiCl in 100 g H2O at 40 C. Is the solution unsaturated, saturated, or supersaturated? Explain your answer. (c) Consider a solution that contains 50. g Li2SO4 in 200. g H2O at 50 C. Is this solution unsaturated, saturated, or supersaturated? Explain your answer. Figure 13.10 Solubility of ionic compounds versus temperature.arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY