(a) Interpretation: The atoms of a main-group element in period 4 that is larger than an atom of arsenic ( Z = 33 ) are to be stated. Concept introduction: On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller. On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

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Answer 1

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Chapter 11, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The atoms of a main-group element in period 4 that is larger than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Interpretation Introduction

(b)

Interpretation:

The atoms of a main-group element in period 4 that is smaller than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

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Answer 2

Question

Chapter 11, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The atoms of a main-group element in period 4 that is larger than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Interpretation Introduction

(b)

Interpretation:

The atoms of a main-group element in period 4 that is smaller than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

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Answer 3

Question

Chapter 11, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The atoms of a main-group element in period 4 that is larger than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Interpretation Introduction

(b)

Interpretation:

The atoms of a main-group element in period 4 that is smaller than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

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Answer 4

Question

Chapter 11, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The atoms of a main-group element in period 4 that is larger than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Interpretation Introduction

(b)

Interpretation:

The atoms of a main-group element in period 4 that is smaller than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

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Answer 5

Chapter 11, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The atoms of a main-group element in period 4 that is larger than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Interpretation Introduction

(b)

Interpretation:

The atoms of a main-group element in period 4 that is smaller than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Answer 6

Chapter 11, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The atoms of a main-group element in period 4 that is larger than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Answer 7

Chapter 11, Problem 61E

Interpretation Introduction

(a)

Interpretation:

The atoms of a main-group element in period 4 that is larger than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The atoms of a main-group element in period 4 that is smaller than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The atoms of a main-group element in period 4 that is smaller than an atom of arsenic (Z=33) are to be stated.

Concept introduction:

On moving from left to right in a periodic table, the effective nuclear charge increases. The effective nuclear charge pulls the valence electrons closer to the nucleus. Thus, the atom becomes smaller.

On moving from top to bottom in the group, the higher principal energy levels become farther from the nucleus. Therefore, the effective nuclear charge cannot pull the valence electrons closer to the nucleus. Thus, the atom size becomes larger.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11 - Prob. 1E Ch. 11 - Prob. 2E Ch. 11 - Identify measurable wave properties that are used...Ch. 11 - Prob. 4E Ch. 11 - Which among the following are not quantized? a...Ch. 11 - Which of the following are quantized? a canned...Ch. 11 - Prob. 7E Ch. 11 - In the Bohr model of the hydrogen atom, the...Ch. 11 - Prob. 9E Ch. 11 - Prob. 10E

Solution Summary: The author explains that the atoms of a main-group element in period 4 are larger than arsenic (Z=33).

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