Concept explainers
(a)
Interpretation:
Whether the elements become more metallic or less metallic on moving down a group in the periodic table is to be stated.
Concept introduction:
Those elements that have tendency to form positive ion by losing electrons are called metals. So, metals are electropositive elements. The elements that have tendency to form anions by gaining electrons are called nonmetal. So, nonmetals are electronegative elements.
(b)
Interpretation:
Whether the elements become more metallic or less metallic on moving left to right across a period in the periodic table is to be stated.
Concept introduction:
Those elements that have tendency to form positive ion by losing electrons are called metals. So, metals are electropositive elements. The elements that have tendency to form anions by gaining electrons are called nonmetal. So, nonmetals are electronegative elements.
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Chapter 11 Solutions
Introductory Chemistry: An Active Learning Approach
- Q1. This question is about atomic structure. (a) Write the full electron configuration for each of the following species. CH Fe2+ (b) Write an equation, including state symbols, to represent the process that occurs when the third ionisation energy of manganese is measured. (c) State which of the elements magnesium and aluminium has the lower first ionisation energy Explain your answer. (d) A sample of nickel was analysed in a time of flight (TOF) mass spectrometer. The sample was ionised by electron impact ionisation. The spectrum produced showed three peaks with abundances as set out in the table. m/z Abundance /% 58 61.0 60 29.1 61 9.9 Give the symbol, including mass number, of the ion that would reach the detector first in the sample. Calculate the relative atomic mass of the nickel in the sample. Give your answer to one decimal place. Page 2 of 12 Symbol of ion Relative atomic massarrow_forwardBoron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?arrow_forward(a) Are the elements calcium, barium, and radium in the same group or same period in the periodic table? (b) Are the elements rhodium, cadmium, and tin in the same group or period?arrow_forward
- (a) Identify the number of electrons in the ground-state outer shell of atomic oxygen (atomic number 8).(b) How many electrons are in the ground-state outer shell of fluorine?arrow_forward28. (a) In Figure P7.7, which sphere could represent a Na atom, Nation, and K atom? Provide an explanation for your choice. (b) In Figure P7.7, which sphere could represent an O atom, S atom, and S2- ion? Provide an explanation for your choice. FIGURE P7.7 (b) (c)arrow_forwardQuestion:Consider two elements, Element A and Element B, from the periodic table. Element A is located in Group 1 and Period 3, while Element B is located in Group 16 and Period 2. (a) Which element would have a larger atomic radius, Element A or Element B? Justify your answer. (b) Predict the ionization energy of Element A and Element B. Which element would have a higher ionization energy? Explain your reasoning. (c) Based on their positions in the periodic table, which element would be more likely to form a stable cation? Provide a brief explanation for your choice.arrow_forward
- (c) Silicon (Si) is the most common chemical element in today's semiconductor industry. It has an atomic number of 14 and belongs to the Group IV (4) of the periodic table with its most common isotope being Si-29. (i) (ii) (iii) Explain what an isotope is. How many protons and how many neutrons are in the nucleus of this Silicon isotope? What is the electron configuration of Si?arrow_forward15. (a) b) Identify the element that is described by the following information. Refer to a periodic table if necessary. It is a group 14 (III A) metalloid in the 3rd period. It is a group 15 (VA) metalloid in the 5th period. It is the other metalloid in group 15 (VA). d) It is a halogen that exists in the liquid state at room temperature. 16. What is the relationship between electron arrangement and the organization of elements in the periodic table?arrow_forward(a) Write out the full electron configuration of Calcium (Ca). (b) How many electrons are in the n=3 shell of Calcium?arrow_forward
- Two main-group elements are highlighted in the outline of the Periodic Table below: What can you say about these elements without knowing exactly which they are? Use that knowledge to answer the questions in the following table, if possible. Important: do not try to figure out exactly which elements are marked, and then use your knowledge of the properties of each specific element. You don't need to. You will also be marked wrong for any answer, correct or not, that can't be determined from the rough location of each marked element in the Periodic Table. Element X Element Y Which element in the gas phase is more likely to glow green or yellow in a flame? X 5 O Can't say without more information. O Element X Which element is more likely to form an ionic compound with chlorine? O Element Y O Can't say without more information. O Element X Which element in the solid state is probably brittle, so that it breaks before bending? Element Y Can't say without more information. Explanation Checkarrow_forward18. (a) What did Ernest Rutherford observe during his experiments? (b) What did Niels Bohr observe during his experiments? (c) How did the work of each scientist contribute to the development of the planetary model of the atom? Explain your ideas in at least four (4) sentences.arrow_forwardQ2. This question is about the periodicity of the Period 3 elements. (a) State and explain the general trend in first ionisation energy across Period 3. Give one example of an element which deviates from the general trend in first (b) ionisation energy across Period 3. Explain why this deviation occurs. Page 3 of 12 (c) The table shows successive ionisation energies of an element Y in Period 3. lonisation number 1 2 3 4 5 6 7 8 lonisation energy kJ mol- 1000 2260 3390 4540 6990 8490 27 100 31 700 Identify element Y Explain your answer using data from the table. (d) Identify the Period 3 element that has the highest melting point. Explain your answer by reference to structure and bonding.arrow_forward
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