
Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 11, Problem 21E
Interpretation Introduction
Interpretation:
The number of orbitals in the
Concept introduction:
According to the
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
36) Complete the following multi-step reactions showing applications of enolate ions arising from ketones,
esters, malonic ester, and keto ester, etc.
(30 pts)
(1)
A
NaOH, H₂O+
heat
A
NaOEt
EtO
OEt
(11)
EOH, H+
H.
B
LDA, H₂O+
-78°C
B
(i) NaOMe, Et-Br
(ii) H₂O+, heat
EtOOC
(III)
COOEt
B
A
(i) NaOEt
LiAlH
4-bromo-2-butene
H₂O+
(ii) H3O+, heat
Write the mechanism for Aldol Condensation (I A or B), and Claisen Condensation (II A).
31) Complete two sets of reactions involving (R)-4-methyl-pent-2-ol producing racemic mixture of tertiary
alcohols (D) and ketone derivative (C). Illustrate the mechanism of B and C or D.
(25 pts)
O
OH
0
K2Cr2O7
Ph-CH2-Br, Mg,
H2SO4
THF, H3O*
(A)
(D)
Racemic mixture
TsCl, Py
(B)
KCN, DMSO
Ph-CH2-Br, Mg,
THF, H3O+
(C)
Mechanism for reactions B and C:
Manoharan Mariappan, Ph.D., Dept. of Natur. Sci., NFC, Tallahassee, FL
33) Synthesize the aromatic compound containing para-substituted carbonyl compound starting from
benzene. Illustrate the mechanism for reaction A.
1)
NU
(25 pts)
A
FeCl
B
(i) HNO3, H2SO4
(II) Sn, HCl(aq)
NH₂
NO₂-D NH₂
(i) MeCO2Me, heat
C
(ii) K2Cr2O7/H2SO4
D
(ii) SOCl2
(iii) 2 Et-NH2
Mechanism for reaction for the nitration of alkyl benzene (B-i):
Characterize the product compound arising from the reaction D by IR and IH NMR spectral data:
IR data (cm):
'H NMR data: Draw the structure and assign the chemical shift with the spin-splitting.
Chapter 11 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 11 - Prob. 1ECh. 11 - Prob. 2ECh. 11 - Identify measurable wave properties that are used...Ch. 11 - Prob. 4ECh. 11 - Which among the following are not quantized? a...Ch. 11 - Which of the following are quantized? a canned...Ch. 11 - Prob. 7ECh. 11 - In the Bohr model of the hydrogen atom, the...Ch. 11 - Prob. 9ECh. 11 - Prob. 10E
Ch. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - Prob. 19ECh. 11 - How many sublevels are there in an atom with n=4?Ch. 11 - Prob. 21ECh. 11 - Prob. 22ECh. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - The principal energy level with n=6 contains six...Ch. 11 - Although we may draw the 4s orbital with the shape...Ch. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Is the quantum mechanical model of the atom...Ch. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - What element has the electron configuration...Ch. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - What is meant by [Ne] in [Ne]3s23p1?Ch. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - Use a noble gas core to write the electron...Ch. 11 - a Write the complete ground state electron...Ch. 11 - 55. Why are valence electrons important?Ch. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - . Using only the periodic table, arrange the...Ch. 11 - Prob. 63ECh. 11 - Prob. 64ECh. 11 - Prob. 65ECh. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - Using only the periodic table, arrange the...Ch. 11 - Prob. 69ECh. 11 - Using only the periodic table, arrange the...Ch. 11 - Prob. 71ECh. 11 - Give the symbol for an element that is: a a...Ch. 11 - Prob. 73ECh. 11 - a What is the name of the alkali metal that is in...Ch. 11 - Prob. 75ECh. 11 - Which of the following describes the element Ba?...Ch. 11 - Prob. 77ECh. 11 - Which of the following describes the element Br?...Ch. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Prob. 85ECh. 11 - Prob. 86ECh. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - Prob. 90ECh. 11 - Prob. 91ECh. 11 - Determine whether each statement that follows is...Ch. 11 - Prob. 93ECh. 11 - Prob. 94ECh. 11 - Prob. 95ECh. 11 - Prob. 96ECh. 11 - Prob. 97ECh. 11 - Prob. 98ECh. 11 - Prob. 99ECh. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - Prob. 102ECh. 11 - Prob. 103ECh. 11 - Prob. 104ECh. 11 - Prob. 105ECh. 11 - Prob. 106ECh. 11 - Prob. 107ECh. 11 - Prob. 108ECh. 11 - Prob. 109ECh. 11 - Prob. 11.1TCCh. 11 - Prob. 11.2TCCh. 11 - Prob. 11.3TCCh. 11 - Prob. 11.4TCCh. 11 - Prob. 11.5TCCh. 11 - Prob. 1CLECh. 11 - Prob. 2CLECh. 11 - Prob. 3CLECh. 11 - Prob. 4CLECh. 11 - Prob. 5CLECh. 11 - Prob. 6CLECh. 11 - Prob. 7CLECh. 11 - Prob. 8CLECh. 11 - Prob. 9CLECh. 11 - Write the electron configuration of the highest...Ch. 11 - Prob. 2PECh. 11 - Prob. 3PECh. 11 - Prob. 4PECh. 11 - Prob. 5PECh. 11 - Prob. 6PECh. 11 - Prob. 7PE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Write structural formulas for the major products by doing addition reactions 1. You must add H2 as Pt is catalyst it does not take part in reactions only speed up the process H₂ CH2=CH-CH3 Pt 2. Add HCI break it into H and Cl CH3 HCI 3. Add Br2 only CC14 is catalyst CH3-CH=CH2 B12 CCl4 4. Add water to this and draw major product, H2SO4 is catalyst you have add water H20 in both the reaction below H₂SO4 CH3-CH=CH2 CH3 H2SO4/H₂O CH3-C=CH2 reflux ?arrow_forwardPlan the synthesis of the following compound using the starting material provided and any other reagents needed as long as carbon based reagents have 3 carbons or less. Either the retrosynthesis or the forward synthesis (mechanisms are not required but will be graded if provided) will be accepted if all necessary reagents and intermediates are shown (solvents and temperature requirements are not needed unless specifically involved in the reaction, i.e. DMSO in the Swern oxidation or heat in the KMnO4 oxidation). H Harrow_forwardHint These are benzene substitution reactions. ALCI3 and UV light are catalyst no part in reactions and triangle A means heating. A. Add ethyl for Et in benzene ring alkylation reaction EtCl = CH3CH2CL 1) EtC1 / AlCl3 / A ? B: Add Br to benzene ring ( substitution) 2) Br₂ / uv light ? C Add (CH3)2 CHCH2 in benzene ring ( substitution) (CH3)2CHCH,C1 / AICI, ?arrow_forward
- Draw the mechanism to make the alcohol 2-hexanol. Draw the Mechanism to make the alcohol 1-hexanol.arrow_forwardDraw the mechanism for the formation of diol by starting with 1-pentanal in... basic conditions then acidic conditions then draw the mechanism for the formation of a carboxylic acid from your product.arrow_forwardIdentify each chiral carbon as either R or S. Identify the overall carbohydrates as L or Darrow_forward
- Ethers can be formed via acid-catalyzed acetal formation. Draw the mechanism for the molecule below and ethanol.arrow_forwardHOCH, H HO CH-OH OH H OH 11 CH₂OH F II OH H H 0 + H OHarrow_forwardDraw the mechanism for the formation of diol by starting with one pen and all in... basic conditions then acidic conditions then draw the mechanism for the formation of a carboxylic acid from your product.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Quantum Numbers, Atomic Orbitals, and Electron Configurations; Author: Professor Dave Explains;https://www.youtube.com/watch?v=Aoi4j8es4gQ;License: Standard YouTube License, CC-BY
QUANTUM MECHANICAL MODEL/Atomic Structure-21E; Author: H to O Chemistry;https://www.youtube.com/watch?v=mYHNUy5hPQE;License: Standard YouTube License, CC-BY