Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
expand_more
expand_more
format_list_bulleted
Question
Chapter 10.5, Problem 11E
Interpretation Introduction
Interpretation:The manner reaction mixture should be analyzed periodically so as to determine the completion of reaction should be outlined.
Concept introduction:The general mechanism for the reaction between
The easiest protocol that can be followed to monitor a reaction is TLC analysis.TLC plate is composed of a thin adsorbent layer along with binders such as calcium sulfate for cohesion between adsorbent and the plate. It works on the system of partition equilibrium that involves adsorption to different degrees over the stationary phase of the TLC plate. A suitable solvent system or eluent is chosen that can easily dissolve analytes but not bonds all of them entirely. The solvent system must not be highly polar so as to prevent the affinity of solutes in the mobile phase only.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Explain the initial velocities method associated with the isolation method to experimentally determine the reaction velocity laws. b) Explain which characteristics the components of a reaction need to present so that the kinetic study can be carried out by i) UV-Vis spectrophotometry; ii) pressure measurements; iii) pH measurements.
5 Br-(aq) + BrO3-(aq) + 6 H+(aq)--> 3 Br2(aq) + 3 H2O(l);
(a) write the expressions of the reaction rates mathematically in terms of
(i) the disappearance of Br- (Reactant);
(ii) the disappearance of BrO3- (Reactant), and
(iii) the formation of Br2 (Product).
(b) What are the stoichiometric relationships (rationalization) of the various rates for this reaction? (e.g. Product C formation is 2x faster than Reactant A disappearance/decomposition.)
(g)
How does simple collision theory (SCT) for reaction kinetics qualitatively
predict the Arrhenius temperature dependence of the rate coefficient?
Explain BRIEFLY the principal deficiencies of SCT. A derivation of more
complex theories is not needed.
Chapter 10 Solutions
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Ch. 10.2 - Prob. 1ECh. 10.2 - Prob. 2ECh. 10.2 - Prob. 3ECh. 10.2 - Prob. 4ECh. 10.2 - Prob. 5ECh. 10.2 - Prob. 6ECh. 10.2 - Prob. 7ECh. 10.2 - Prob. 8ECh. 10.2 - Prob. 9ECh. 10.2 - Prob. 10E
Ch. 10.2 - Prob. 11ECh. 10.2 - Prob. 12ECh. 10.2 - Prob. 13ECh. 10.2 - Prob. 14ECh. 10.2 - Prob. 15ECh. 10.2 - Prob. 16ECh. 10.2 - Prob. 17ECh. 10.3 - Prob. 1ECh. 10.3 - Prob. 2ECh. 10.3 - Prob. 3ECh. 10.3 - Prob. 4ECh. 10.3 - Prob. 5ECh. 10.3 - Prob. 6ECh. 10.3 - Prob. 7ECh. 10.3 - Prob. 8ECh. 10.3 - Prob. 9ECh. 10.3 - Prob. 10ECh. 10.3 - Prob. 11ECh. 10.3 - Prob. 12ECh. 10.3 - Prob. 13ECh. 10.3 - Prob. 14ECh. 10.3 - Prob. 15ECh. 10.3 - Prob. 16ECh. 10.3 - Prob. 17ECh. 10.3 - Prob. 18ECh. 10.3 - Prob. 19ECh. 10.3 - Prob. 20ECh. 10.3 - Prob. 21ECh. 10.3 - Prob. 22ECh. 10.3 - Prob. 23ECh. 10.3 - Prob. 24ECh. 10.3 - Prob. 25ECh. 10.3 - Prob. 26ECh. 10.3 - Prob. 27ECh. 10.3 - Prob. 28ECh. 10.3 - Prob. 29ECh. 10.3 - Prob. 30ECh. 10.3 - Prob. 31ECh. 10.3 - Prob. 32ECh. 10.5 - Prob. 1ECh. 10.5 - Prob. 2ECh. 10.5 - Prob. 3ECh. 10.5 - Prob. 4ECh. 10.5 - Prob. 5ECh. 10.5 - Prob. 6ECh. 10.5 - Prob. 7ECh. 10.5 - Prob. 8ECh. 10.5 - Prob. 9ECh. 10.5 - Prob. 10ECh. 10.5 - Prob. 11ECh. 10.5 - Prob. 12ECh. 10.5 - Prob. 14ECh. 10.5 - Prob. 15ECh. 10.5 - Prob. 16ECh. 10.5 - Prob. 17ECh. 10.5 - Prob. 18ECh. 10.5 - Prob. 19ECh. 10.5 - Prob. 20ECh. 10.5 - Prob. 23ECh. 10.6 - Prob. 1ECh. 10.6 - Prob. 2ECh. 10.6 - Prob. 3ECh. 10.6 - Prob. 4ECh. 10.6 - Prob. 5ECh. 10.6 - Prob. 6ECh. 10.6 - Prob. 7ECh. 10.6 - Prob. 8ECh. 10.6 - Prob. 9ECh. 10.6 - Prob. 10ECh. 10.6 - Prob. 11ECh. 10.6 - Prob. 12ECh. 10.6 - Prob. 13ECh. 10.6 - Prob. 14ECh. 10.6 - Prob. 15ECh. 10.6 - Prob. 16ECh. 10.6 - Prob. 17ECh. 10.6 - Prob. 18ECh. 10.6 - Prob. 20ECh. 10.6 - Prob. 21ECh. 10.6 - Prob. 22ECh. 10.6 - Prob. 23ECh. 10.6 - Prob. 24ECh. 10.6 - Prob. 25ECh. 10.6 - Prob. 26ECh. 10.6 - Prob. 28ECh. 10.6 - Prob. 29ECh. 10.6 - Prob. 30ECh. 10.7 - Prob. 1ECh. 10.7 - Prob. 2ECh. 10.7 - Prob. 3ECh. 10.7 - Prob. 4ECh. 10.7 - Prob. 5ECh. 10.7 - Prob. 6ECh. 10.7 - Prob. 7ECh. 10.7 - Prob. 8ECh. 10.7 - Prob. 9ECh. 10.7 - Prob. 10ECh. 10.7 - Prob. 11ECh. 10.7 - Prob. 12ECh. 10.8 - Prob. 1ECh. 10.8 - Prob. 2ECh. 10.8 - Prob. 4ECh. 10.8 - Prob. 5ECh. 10.8 - Prob. 6ECh. 10.8 - Prob. 7ECh. 10.8 - Prob. 8ECh. 10.8 - Prob. 9ECh. 10.8 - Prob. 10ECh. 10.8 - Prob. 11ECh. 10.8 - Prob. 12ECh. 10.8 - Prob. 13ECh. 10.8 - Prob. 14ECh. 10.8 - Prob. 15E
Knowledge Booster
Similar questions
- Write two differences between ‘order of reaction’ and ‘molecularity of reaction’.arrow_forward(2) The reaction-rate data given below were obtained using a batch reaction system for the reaction A→products. Plot the data in appropriate form to test the fit for zero- and first-order kinetics. From the plot that gives the best fit, determine the appropriate reaction rate constant (remember the units). Time, min CA, (g/m3) 0 30 0.5 25.4 1 21.6 2 16.9 4 13.1 8 8.3 16 3.2 32 0.31arrow_forwardexplain the role of reaction dynamics and quantitative chemistry in enhancing the productivity of industrial processesarrow_forward
- Create a procedure outline for calculating the activation energy of an iodine clock reaction, an example (this example has to do with determining rate equation for the clock reaction by measuring rates of reactions using different initial concentrations) : Measure reaction rate as a function of iodide I– concentration by decreasing initial iodide concentration while keeping all other concentrations constant. Use water to make up for volume loss for reduced amount of iodide stock solution. Measure reaction rate as a function of persulfate S2O 2– 8 concentration by decreasing initial persulfate concentration while keeping all other concentrations constant. Use water to make up for volume loss for reduced amount of persulfate stock solution. Use linear regression on log10 Rate as a function of log10[I– ]i or log10[S2O 2– 8 ]i for each reaction series to determine order for each reactant (exponent for the concentration in the rate law) Use measured rates, initial concentrations, and…arrow_forwardWhat is the difference between order of reaction and molecularity ?arrow_forward11) Explain fully using the collision theory. How the rate of reaction will change due to the partial evaporation of the solvent from the first reagent, before the addition of the second reagent? CCALE of 66001 Clasarrow_forward
- Please give me very detailed solution.arrow_forward(b) Discuss, with reasoning, the validity of the following statements in NO MORE than 90 words for each part: (iii) Evidence that a bimolecular reaction occurs via a harpoon mechanism is that the observed rate of reaction is faster than predicted with simple collision theory.arrow_forwardWrite the steps of ‘Modern Adsorption Theory of Heterogenous Catalysis.’arrow_forward
- Chemistryarrow_forwardA4 • How can you use quantitative chemistry and reaction dynamics to explain and optimize industrial processes and reactions that happen in everyday life?arrow_forwardalready have the answer just need a more detailed break down of how to solve. specifically I dont quite get how my profesor got the number highlighted in yellow.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning