Question 8Please predict the products for each of the following reactions.Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).If a mixture of enantiomers is formed, please draw all the enantiomers.Br2(CH3)2SCH₂OH1.032. DMSKMnO4, NaOHcoldHIPd or Pt (catalyst)HBrROOR (peroxide)H₂OH2SO4HCI20181716151412 11 101. BH, THF2. H₂O2, NaOHBr2Br2MCPBA1. Os042. H₂O2CHCO3H(peroxyacid)МСРВАMCPBAH3O+D₂ (deuterium)Pd or Ni (catalyst)H₂OBH3⚫THFBr₂ABrBď ďOHBr+BrOH0Br"OHBrDOH"BrOHď ď ď ď"OH"BrOHBrABCD

Question 8 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH BOH 1.03 2. DMS KMnO4, NaOH cold HI 20 Pd or Pt (catalyst) HBr ROOR (peroxide) Н2О H₂SO4 MCPBA 1. Os04 2. H₂O2 CH3CO₂H (peroxyacid) 17 16 15 MCPBA MCPBA H3O+ 14 18 12 11 10 D₂ (deuterium) Pd or Ni (catalyst) Br2 H₂O BH3⚫THF Bra HCI 1. BH3.THF 2. H₂O2, NaOH Br2 A B 0 D Br ď ď OH Br + Br OH Br "OH Br "Br OH ď ď ď ď "OH 'Br OH Br A B C D

Question 8 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH BOH 1.03 2. DMS KMnO4, NaOH cold HI 20 Pd or Pt (catalyst) HBr ROOR (peroxide) Н2О H₂SO4 MCPBA 1. Os04 2. H₂O2 CH3CO₂H (peroxyacid) 17 16 15 MCPBA MCPBA H3O+ 14 18 12 11 10 D₂ (deuterium) Pd or Ni (catalyst) Br2 H₂O BH3⚫THF Bra HCI 1. BH3.THF 2. H₂O2, NaOH Br2 A B 0 D Br ď ď OH Br + Br OH Br "OH Br "Br OH ď ď ď ď "OH 'Br OH Br A B C D

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question 7
14. Subject :- Chemistry
Predict the product(s) of the following reactions. Indicate stereochemistry where appropriate. Note that each arrow is a separate reaction, so there are 6 reactions in total and six different
Question 16 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH3OH H₂ Pd or Pt (catalyst) 2. (CH3)2S 2. DMS 1.03 KMnO4, NaOH cold 18 17 HI 16 15 20 1 2 HBr ROOR (peroxide) H₂O H2SO4 HCI 50 6 1. BH3⚫THF 7 8 2. H₂O2, NaOH 14 12 11 10 MCPBA 1. OsO4 2. H₂O₂ CH3CO3H (peroxyacid) A B 8.8 Α A B Br2 Br2 H₂O BH3⚫THF Br Pd or Ni (catalyst) D₂ (deuterium) FIQH MCPBA H₂O C D 0 D
Question 2 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O2 CH3CO₂H (peroxyacid) MCPBA 2. (CH3)2S 20 19 18 17 16 15 H₂ Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH 14 Br2 13 12 11 10 H₂O Br2 BH3⚫THF Bra F+OH Pd or Ni (catalyst) D2 (deuterium) A B C D Br Br Br ď ď H "Br "Br 3.8 Α ABCD
What would be the products of these synthesizes, drawn out
Reactions Predict the product or products of the following reactions. If more than one product, indicate which one is the major product, if possible. Be sure to indicate stereochemistry and regiochemistry, where necessary. If no reaction, write “no reaction” as the product.
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn-vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. A 8.8 О А B D ""Br Br₂ CH3OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Os04 2. H₂O₂ B 1.03 2. (CH3)2S 17 16 78 Br "Br 15 CH₂CO3H (peroxyacid) 14 19 MCPBA H₂2 Pd or Pt (catalyst) HBr 20 1 2. H₂O* Pd or Ni (catalyst) 2 D₂ (deuterium) с 3 FtOH Br BH3 THF HBr ROOR (peroxide) H₂O H₂SO4 HCI H₂O 1. BH3 THF 2. H₂O₂, NaOH Bra Br₂ H₂O D a a "Br Br aa Br "Br
Question 19 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO4 2. H₂O₂ 18 17 16 CH3CO₂H (peroxyacid) 15 14 Pa or Pt (catalyst) 19 20 1 2 13 12 11 10 Pd or Ni (catalyst) D₂ (deuterium) (deuterium) A B H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br2 Br2 BH3⚫THF H₂O 0 D OCH3 а Br OCH3 Br OCH3 Br Br OCH3 Br OCH3 Br OCH3 de de de of Br OCH3 OCH3 'Br ABCD
Fill in the major products to complete the transformations. Be sure to pay carefulattention to stereochemistry where appropriate. If the major product is a pair of enantiomers or diastereomers be sure to draw them both. And indicate whether you have drawn an enantiomer or a diastereomer. (Don't forget about rearrangement).
Question 9 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI ТСРВА 1. OsO4 2. H₂O₂ sl+H3 19 18 17 16 15 CH3CO₂H (peroxyacid) 14 MCPBA 13
Question 15 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI Pd or Pt (catalyst) 20 1 2 19 18 17 16 15 14 13 12 11 10 MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br2 FIOH Pd or Ni (catalyst) D₂ (deuterium) A B с 000 ABCD ....O D