Question 5 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Pd or Pt (catalyst) 20 12 Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O2 CH3CO₂H 19 18 17 16 15 14 (peroxyacid) 13 MCPBA 2. H₂O 12 11 HBr ROOR (peroxide) H₂O 10 50 H2SO4 HCI 1. BH3.THF 6 2. H₂O2, NaOH Br2 FIOH Pd or Ni (catalyst) D2 (deuterium) Br2 H₂O BH3⚫THF A B с D ४.४ A B C 3.8 ४.४
Question 5 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Pd or Pt (catalyst) 20 12 Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O2 CH3CO₂H 19 18 17 16 15 14 (peroxyacid) 13 MCPBA 2. H₂O 12 11 HBr ROOR (peroxide) H₂O 10 50 H2SO4 HCI 1. BH3.THF 6 2. H₂O2, NaOH Br2 FIOH Pd or Ni (catalyst) D2 (deuterium) Br2 H₂O BH3⚫THF A B с D ४.४ A B C 3.8 ४.४
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
Question 5
2. (CH3)2S
Br2
CH₂OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
MCPBA
Pd or Pt (catalyst)
HBr
ROOR (peroxide)
H₂O
20
12
19
18
17
16
15
1. OsO4
2. H₂O2
CH3CO₂H
14
13
(peroxyacid)
12
11
10
H2SO4
HCI
5
1. BH3.THF
6
2. H₂O2, NaOH
Br2
Pd or Ni (catalyst)
D2 (deuterium)
FIOH
MCPBA
2. H₂O
Br2
H₂O
BH3⚫THF
A
B
с
D
8.8
A
B
C
3.8
४.४
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