Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn-vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. O A 8.8 O B O A O C CH₂OH Br₂ 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Os04 2. H₂O₂ 1.03 2. (CH3)2S 17 78 16 15 B 19 20 14 24 13 CH₂CO3H (peroxyacid) . MCPBA -H₂O* Pd or Pt (catalyst) HBr 11 10 5 Pd or Ni (catalyst) D₂ (deuterium) Bra EtOH BH 3 THF HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH3-THF 2. H₂O₂, NaOH Brz Br₂ H₂O D 8.8 8.8

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn-vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
O A
O
A
8.8
B
с
D
Br₂
CH3OH
2. (CH3)2S
1.03
2. DMS
KMnO4, NaOH
cold
HI
mCPBA
1. OsO4
2. H₂O2
17
16
15
CH3CO3H
(peroxyacid)
B
79
13
MCPBA
2. H₂O+
H₂
Pd or Pt (catalyst)
20 1 2 3 4
5
Pd or Ni (catalyst)
D₂ (deuterium)
EtOH
Br₂
C
BH3 THF
8.8
HBr
ROOR (peroxide)
H₂O
H₂SO4
HCI
"""Cl
1. BH3-THF
2. H₂O2, NaOH
Br₂
Br₂
H₂O
D
Cl
Transcribed Image Text:Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn-vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. O A O A 8.8 B с D Br₂ CH3OH 2. (CH3)2S 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO4 2. H₂O2 17 16 15 CH3CO3H (peroxyacid) B 79 13 MCPBA 2. H₂O+ H₂ Pd or Pt (catalyst) 20 1 2 3 4 5 Pd or Ni (catalyst) D₂ (deuterium) EtOH Br₂ C BH3 THF 8.8 HBr ROOR (peroxide) H₂O H₂SO4 HCI """Cl 1. BH3-THF 2. H₂O2, NaOH Br₂ Br₂ H₂O D Cl
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