Please predict the products for each of the following reactions.Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).If a mixture of enantiomers is formed, please draw all the enantiomers. 1.032. DMSKMnO4, NaOHcoldHIBr₂CH3OHmCPBA1. Oso42. H₂O2HOAماعCمع1.032. (CH3)2S181716151914CH3CO3H(peroxyacid)13H₂Pd or Pt (catalyst)HBr20 1212 11 101. МСРВА2. H3O*345678Pd or Ni (catalyst)D2 (deuterium)EtOHBr₂BH 3 THFOHHBrROOR (peroxide)H₂OH₂SO4BHCID1. BH 3 THF2. H₂O2, NaOHBr₂H₂OBr₂

The major organic product of the reaction is D which is explained via the following…

1.03 2. DMS KMnO4, NaOH cold HI Br₂ CH3OH mCPBA 1. Oso4 2. H₂O2 HO A ماع C مع 1.03 2. (CH3)2S 18 17 16 15 19 14 CH3CO3H (peroxyacid) 13 H₂ Pd or Pt (catalyst) HBr 20 1 2 12 11 10 1. МСРВА 2. H3O* 3 4 5 6 7 8 Pd or Ni (catalyst) D2 (deuterium) EtOH Br₂ BH 3 THF OH HBr ROOR (peroxide) H₂O H₂SO4 B HCI D 1. BH 3 THF 2. H₂O2, NaOH Br₂ H₂O Br₂

1.03 2. DMS KMnO4, NaOH cold HI Br₂ CH3OH mCPBA 1. Oso4 2. H₂O2 HO A ماع C مع 1.03 2. (CH3)2S 18 17 16 15 19 14 CH3CO3H (peroxyacid) 13 H₂ Pd or Pt (catalyst) HBr 20 1 2 12 11 10 1. МСРВА 2. H3O* 3 4 5 6 7 8 Pd or Ni (catalyst) D2 (deuterium) EtOH Br₂ BH 3 THF OH HBr ROOR (peroxide) H₂O H₂SO4 B HCI D 1. BH 3 THF 2. H₂O2, NaOH Br₂ H₂O Br₂

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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