A Br₂ CH3OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Oso4 2. H₂O2 B 1.03 2. (CH3)2S 18 17 16 15 19 14 13 CH3CO3H (peroxyacid) H₂ Pd or Pt (catalyst) HBr 20 1 12 11 1. МСРВА 2. H3O+ Pd or Ni (catalyst) 2 10 3 9 5 6 2 D₂ (deuterium) EtOH Br₂ BH 3 THF I I I 1 I HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH 3 THF 2. H₂O2, NaOH Br₂ I I Br₂ H₂O I I I 1. I I I D I I I I I 1 I I I I I I I I

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please predict the products for each of the following reactions.

Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).

If a mixture of enantiomers is formed, please draw all the enantiomers.

A
Br₂
CH3OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
mCPBA
1. Oso4
2. H₂O2
B
1.03
2. (CH3)2S
18
17
16
15
19
14
13
CH3CO3H
(peroxyacid)
H₂
Pd or Pt (catalyst)
HBr
20 1
12 11
1. МСРВА
2. H3O+
Pd or Ni (catalyst)
2
10
3
9
5
6
2
D₂ (deuterium)
EtOH
Br₂
BH 3 THF
I
I
I
1
I
HBr
ROOR (peroxide)
H₂O
H₂SO4
HCI
1. BH 3 THF
2. H₂O2, NaOH
Br₂
I
I
Br₂
H₂O
I
I
I
1.
I
I
I
D
I
I
I
I
I
1
I
I
I
I
I
I
I
I
Transcribed Image Text:A Br₂ CH3OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Oso4 2. H₂O2 B 1.03 2. (CH3)2S 18 17 16 15 19 14 13 CH3CO3H (peroxyacid) H₂ Pd or Pt (catalyst) HBr 20 1 12 11 1. МСРВА 2. H3O+ Pd or Ni (catalyst) 2 10 3 9 5 6 2 D₂ (deuterium) EtOH Br₂ BH 3 THF I I I 1 I HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH 3 THF 2. H₂O2, NaOH Br₂ I I Br₂ H₂O I I I 1. I I I D I I I I I 1 I I I I I I I I
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