A Br₂ CH3OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Os04 2. H₂O₂ 2. (CH3)2S 17 16 1.03 18 15 B 19 14 CH3CO3H (peroxyacid) 13 Br œœ 'OEt 20 1 1. МСРВА 2. H3O+ H₂ Pd or Pt (catalyst) HBr Br 12 11 10 OEt 2 Pd or Ni (catalyst) D2 (deuterium) 3 4 5 6 7 8 EtOH Br₂ C Br OEt Br do you do Br 'OEt OEt BH 3 THF Br œ H₂O H₂SO4 HBr ROOR (peroxide) OEt HCI 1. BH 3 THF 2. H₂O2, NaOH Br₂ Br₂ H₂O D OEt dom Br + d OEt "Br

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please predict the products for each of the following reactions.

Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).

If a mixture of enantiomers is formed, please draw all the enantiomers.

A
Br₂
CH3OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
mCPBA
1. Os04
2. H₂O₂
2. (CH3)2S
17
16
1.03
18
15
B
19
14
CH3CO3H
(peroxyacid)
13
Br
œœ
'OEt
20 1
1. МСРВА
2. H3O+
H₂
Pd or Pt (catalyst)
HBr
Br
12 11 10
OEt
2
Pd or Ni (catalyst)
D2 (deuterium)
3
4
5
6
7
8
EtOH
Br₂
C
Br
OEt
Br
do you do
Br
'OEt
OEt
BH 3 THF
Br
œ
H₂O
H₂SO4
HBr
ROOR (peroxide)
OEt
HCI
1. BH 3 THF
2. H₂O2, NaOH
Br₂
Br₂
H₂O
D
OEt
dom
Br
+
d
OEt
"Br
Transcribed Image Text:A Br₂ CH3OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Os04 2. H₂O₂ 2. (CH3)2S 17 16 1.03 18 15 B 19 14 CH3CO3H (peroxyacid) 13 Br œœ 'OEt 20 1 1. МСРВА 2. H3O+ H₂ Pd or Pt (catalyst) HBr Br 12 11 10 OEt 2 Pd or Ni (catalyst) D2 (deuterium) 3 4 5 6 7 8 EtOH Br₂ C Br OEt Br do you do Br 'OEt OEt BH 3 THF Br œ H₂O H₂SO4 HBr ROOR (peroxide) OEt HCI 1. BH 3 THF 2. H₂O2, NaOH Br₂ Br₂ H₂O D OEt dom Br + d OEt "Br
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