Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both If a mixture of enantiomers is formed, please draw all the enantiomers. 1.03 2. DMS Br2 CH₂OH KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH,COSH (peroxyacid) 1. MCPBA 1. 03 2. (CH3)2S ZH HBr Pd or Pt (catalyst) 19 20 1 2 106 45 HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH3.THF 2. H2O2, NaOH Br2 18 17 16 655 15 2. H₂O* 14 12 11 10 6 Br₂ H₂O BH3⚫THF Br2 Pd or Ni (catalyst) D₂ (deuterium) EtOH A B H Br Br H 'Br с D Br میں ملی H "Br
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both If a mixture of enantiomers is formed, please draw all the enantiomers. 1.03 2. DMS Br2 CH₂OH KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH,COSH (peroxyacid) 1. MCPBA 1. 03 2. (CH3)2S ZH HBr Pd or Pt (catalyst) 19 20 1 2 106 45 HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH3.THF 2. H2O2, NaOH Br2 18 17 16 655 15 2. H₂O* 14 12 11 10 6 Br₂ H₂O BH3⚫THF Br2 Pd or Ni (catalyst) D₂ (deuterium) EtOH A B H Br Br H 'Br с D Br میں ملی H "Br
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Question 2
Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
Br2
CH₂OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
MCPBA
1. OsO4
2. H₂O2
CH3CO₂H
(peroxyacid)
MCPBA
2. (CH3)2S
20
19
18
17
16
15
H₂
Pd or Pt (catalyst)
HBr
ROOR (peroxide)
H₂O
H2SO4
HCI
1. BH3⚫THF
2. H₂O2, NaOH
14
Br2
13
12
11 10
H₂O
Br2
BH3⚫THF
Bra
F+OH
Pd or Ni (catalyst)
D2 (deuterium)
A
B
C
D
Br
Br
Br
ď ď
H
"Br
"Br
3.8
Α
ABCD
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