Question 1 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Hint: In this case you must choose the best answer to demonstrate the stereochemistry of H2 addition. 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA Br2 CH₂OH 2. (CH3)2S 19 18 17 16 15 2. H₂O+ 14 13 H₂ Pd or Pt (catalyst) 20 1 2 12 11 10 HBr ROOR (peroxide) H₂O H2SO4 HCI 5 6 1. BH3.THF 2. H2O2, NaOH Br₂ Br2 H₂O BH3⚫THF FIOH Bra Pd or Ni (catalyst) D₂ (deuterium) A B с D ď "H 8.8 Α ABCD

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Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.