Question 1 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Hint: In this case you must choose the best answer to demonstrate the stereochemistry of H2 addition. 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA Br2 CH₂OH 2. (CH3)2S 19 18 17 16 15 2. H₂O+ 14 13 H₂ Pd or Pt (catalyst) 20 1 2 12 11 10 HBr ROOR (peroxide) H₂O H2SO4 HCI 5 6 1. BH3.THF 2. H2O2, NaOH Br₂ Br2 H₂O BH3⚫THF FIOH Bra Pd or Ni (catalyst) D₂ (deuterium) A B с D ď "H 8.8 Α ABCD

Question 1 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Hint: In this case you must choose the best answer to demonstrate the stereochemistry of H2 addition. 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA Br2 CH₂OH 2. (CH3)2S 19 18 17 16 15 2. H₂O+ 14 13 H₂ Pd or Pt (catalyst) 20 1 2 12 11 10 HBr ROOR (peroxide) H₂O H2SO4 HCI 5 6 1. BH3.THF 2. H2O2, NaOH Br₂ Br2 H₂O BH3⚫THF FIOH Bra Pd or Ni (catalyst) D₂ (deuterium) A B с D ď "H 8.8 Α ABCD

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

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i’m really confused on these drawing questions as i don’t know how the two catalysts will change the structure