Question 18 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O H₂SO4 20 1 2 19 3 HCI 18 17 5 1. BH, THF 16 6 2. H₂O₂, NaOH 8. Br₂ 12 10 11 Bra CH₂OH 1. 03 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO 2. H₂O₂ нозно (peroxyacid) 15 14 13 H₂O Br2 BH₂⚫THF min OH ОН B six mie ABCD

Question 18 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O H₂SO4 20 1 2 19 3 HCI 18 17 5 1. BH, THF 16 6 2. H₂O₂, NaOH 8. Br₂ 12 10 11 Bra CH₂OH 1. 03 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO 2. H₂O₂ нозно (peroxyacid) 15 14 13 H₂O Br2 BH₂⚫THF min OH ОН B six mie ABCD

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Does a rotation about the carbon-carbon sigma bond always happen in a E1 reaction? If not, why is it happening in this reaction?
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 7 1. CH3)25 HBr ROOR (peroxide) H₂O 14 13 20 1 19 3 18 4 17 16 15 H₂SO4 HCI 6 1. BH3⚫THF 2. H₂O2, NaOH 8 Br₂ 12 11 10 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) Br2 H₂O BH3⚫THF Pd or Ni D₂ (deuterium) FIOH A B Br C Br Br D ď ď ď ď ď Br Br Br Br ***Br Α ABCD Br Br Br Br "Br Br Br Br
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Question 20 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O 201 4 Br₂ CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO4 2. H₂O₂ CH3CO₂H 2. (CH3)2S 19 18 17 16 15 (peroxyacid) 14 13 ماه پناه А ABCD 12 H₂SO4 HCI 11 10 9 1. BH3.THF 2. H₂O2, NaOH Br2 Pd or Ni (catalyst) D2 (deuterium) Br2 H₂O BH3⚫THF OH B D
Draw all the major products resulting from the reactions below, taking into consideration both the regioselectivity and stereoselectivity of the reactions. If pairs of enantiomers form, draw both enantiomers. Br₂ CH3CH₂OH (in large excess) H₂, Pd/C
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 20 HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. Os04 2. H₂O₂ 2. (CH3)2S 17 16 15 CH3CO₂H (peroxyacid) 18 19 Pd or Pt (catalyst) 20 1 2 14 13 9 12 11 10 D2 (deuterium Br2 Br2 H₂O BH3⚫THF Br₂ A B فرمح D ОН ماه چها Α A B C ° D
Question 8
Reactions Predict the product or products of the following reactions. If more than one product, indicate which one is the major product, if possible. Be sure to indicate stereochemistry and regiochemistry, where necessary. If no reaction, write “no reaction” as the product.
Any help with this would be great! Thanks in advance!
Question 14 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 19 18 17 16 Pd or Pt (catalyst) 20 1 2 HBr ROOR (peroxide) H₂O 12 11 10 MCPBA 1. Os04 2. H₂O2 CH3CO₂H (peroxyacid) 15 14 13 A B H₂SO4 HCI 5 6 1. BH3.THF 2. H₂O2, NaOH Pd or Ni (catalyst) D₂ (deuterium) Br2 Br2 H₂O BH3⚫THF C D ...OH OH OH OH OH OH OH "OH "OH OH ° A B OH OH OH OH OH C OH OH OH OH OH D
Question 11 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1. 03 2. DMS KMnO4, NaOH cold HI Pd or Pt (catalyst) 20 19 18 17 16 15 14 13 12 mCPBA 1. OsO4 2. H₂O₂ CH3CHO₂H (peroxyacid) BA A A B ° C D B 2 ROOR HBr (peroxid H₂SO4 HCI 1. BH3.THF 11 10 2. H₂O2, NaOH Br2 2 Pd or Ni (catalyst) D₂ (deuterium) Br₂ H₂O BH3.⚫THF 0 D D
Question 13 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 (CH3)2S CH3OH 1.03 2. DMS KMnO4, NaOH cold HI A B 18 17 16 zu 2 Pd or Pt (catalyst) HBr 19 20 1 HBr ROOR (peroxide) Н20 H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br2 Br2 12 11 10 BH3⚫THF H₂O MCPBA 1. OsO4 2. H₂O2 CH3CO₂H (peroxyacid) MCPBA 15 14 13 C A D Pd or Ni (catalyst) D₂ (deuterium) FIOH B с D OH OH OH "OH