Question 19Please predict the products for each of the following reactions.Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).If a mixture of enantiomers is formed, please draw all the enantiomers.Br2CH3OH1.032. DMSKMnO4, NaOHcoldHIMCPBA1. OsO42. H₂O₂1918171615CH3CO₂H(peroxyacid)1413Pd or Pt (catalyst)201212 11 10D₂ (deuterium)HBrROOR (peroxide)H₂O8H2SO4HCI1. BH3.THF2. H₂O2, NaOHBr2Br2H₂OBH3⚫THFABсDOCH3BrBrOCH3'BrOCH3OCH3BrOCH3BrBrOCH3of de det ofBr"OCH3OCH3""BrАA BCO D

Alkenes are unsaturated hydrocarbons that have double bonds due to which they are reactive and…

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both) If a mixture of enantiomers is formed, please draw all the enantiomers. H₂ Pd or Pt (catalyst) HBr cold 1.03 2. DMS KMnO4, NaOH CH₂OH 1.03 Br₂ 2. (CH3)2S 20 19 18 17 HI 16 15 2 14 13 12 11 10 MCPBA 1. Os04 2. H₂O₂ CH3CO_H (peroxyacid) 1. MCPBA 2. H₂O* A B HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 34 9 569 Br2 H₂O BH3.THF Bra Pd or Ni (catalyst) D2 (deuterium) EtOH C D OCH ☑OCH 'Br Br OCH Br OCH Br OCH3 OCH3 Br Br OCH "OCH OCH3 "Br Br

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both) If a mixture of enantiomers is formed, please draw all the enantiomers. H₂ Pd or Pt (catalyst) HBr cold 1.03 2. DMS KMnO4, NaOH CH₂OH 1.03 Br₂ 2. (CH3)2S 20 19 18 17 HI 16 15 2 14 13 12 11 10 MCPBA 1. Os04 2. H₂O₂ CH3CO_H (peroxyacid) 1. MCPBA 2. H₂O* A B HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 34 9 569 Br2 H₂O BH3.THF Bra Pd or Ni (catalyst) D2 (deuterium) EtOH C D OCH ☑OCH 'Br Br OCH Br OCH Br OCH3 OCH3 Br Br OCH "OCH OCH3 "Br Br

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question 19 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO4 2. H₂O₂ 18 17 16 CH3CO₂H (peroxyacid) 15 14 Pa or Pt (catalyst) 19 20 1 2 13 12 11 10 Pd or Ni (catalyst) D₂ (deuterium) (deuterium) A B H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br2 Br2 BH3⚫THF H₂O 0 D OCH3 а Br OCH3 Br OCH3 Br Br OCH3 Br OCH3 Br OCH3 de de de of Br OCH3 OCH3 'Br ABCD
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Question 15 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI Pd or Pt (catalyst) 20 1 2 19 18 17 16 15 14 13 12 11 10 MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br2 FIOH Pd or Ni (catalyst) D₂ (deuterium) A B с 000 ABCD ....O D
Question 16 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 20 HBr ROOR (peroxide) H₂O H₂SO4 HCI MCPBA 1. OsO4 2. H₂O₂ 18 17 16 15 CH3COJH (peroxyacid) 14 MCPBA 13 12 11 10 D2 (deuterium) 9 8 1. BH3.THF 2. H₂O2, NaOH Br₂ Br2 H₂O BH3⚫THF A B ४.१ A ов C D D α.α α. α
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Question 3 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. H₂ Pd or Pt (catalyst) 120 (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 20 1 2 18 17 16 15 14 13 HBr ROOR (peroxide) H₂O 12 11 10 MCPBA 1. OsO4 2. H₂O2 CH3CO₂H (peroxyacid) MCPBA A H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br₂ Pd or Ni (catalyst) D₂ (deuterium) EtOH B с D Br Br аа Br 'Br 8.8° Br Br 'Br 8.8° Α ABU C D Br 'Br