Question 3Please predict the products for each of the following reactions.Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).If a mixture of enantiomers is formed, please draw all the enantiomers.H₂Pd or Pt (catalyst)120 (CH3)2SBr2CH₂OH1.032. DMSKMnO4, NaOHcoldHI20 1 2181716151413HBrROOR (peroxide)H₂O12 11 10MCPBA1. OsO42. H₂O2CH3CO₂H(peroxyacid)MCPBAAH2SO4HCI1. BH3⚫THF2. H₂O2, NaOHBr2Br2H₂OBH3⚫THFBr₂Pd or Ni (catalyst)D₂ (deuterium)EtOHBсDBrBrааBr'Br8.8°BrBr'Br8.8°ΑABUCDBr'Br

According to the Anti Markovnikov rule, in the presence of peroxide the negative part of the reagent…

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Pd or Pt (catalyst) HBr ROOR (peroxide) Н20 H₂SO4 HCI 1. BH, THF 6 2. H₂O2, NaOH Br₂ BH3⚫THF Br2 H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O2 CH3CO₂H (peroxyacid) ΤΗ 20 1 2 18 17 16 15 14 13 12 11 10 Pd or Ni (catalyst leuterium) D₂ (deuterium EtOH A ABCD Br B Br 8.8 Br Br C Br D αα Br "Br σα Br 'Br

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Pd or Pt (catalyst) HBr ROOR (peroxide) Н20 H₂SO4 HCI 1. BH, THF 6 2. H₂O2, NaOH Br₂ BH3⚫THF Br2 H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O2 CH3CO₂H (peroxyacid) ΤΗ 20 1 2 18 17 16 15 14 13 12 11 10 Pd or Ni (catalyst leuterium) D₂ (deuterium EtOH A ABCD Br B Br 8.8 Br Br C Br D αα Br "Br σα Br 'Br

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question 15 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI Pd or Pt (catalyst) 20 1 2 19 18 17 16 15 14 13 12 11 10 MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br2 FIOH Pd or Ni (catalyst) D₂ (deuterium) A B с 000 ABCD ....O D