Question 14 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 19 18 17 16 Pd or Pt (catalyst) 20 1 2 HBr ROOR (peroxide) H₂O H₂SO4 HCI 6 1. BH3.THF 2. H₂O2, NaOH 12 11 10 MCPBA 1. Os04 2. H₂O2 CH3CO₂H (peroxyacid) 15 14 13 A B Pd or Ni (catalyst) D2 (deuterium) Br2 Br2 H₂O BH3⚫THF C D OH OH OH OH OH OH OH "OH "OH OH OH OH OH OH OH OH OH OH OH "OH A B ° C D

Question 14 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 19 18 17 16 Pd or Pt (catalyst) 20 1 2 HBr ROOR (peroxide) H₂O H₂SO4 HCI 6 1. BH3.THF 2. H₂O2, NaOH 12 11 10 MCPBA 1. Os04 2. H₂O2 CH3CO₂H (peroxyacid) 15 14 13 A B Pd or Ni (catalyst) D2 (deuterium) Br2 Br2 H₂O BH3⚫THF C D OH OH OH OH OH OH OH "OH "OH OH OH OH OH OH OH OH OH OH OH "OH A B ° C D

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question 38
Show the product(s) from each of the following reactions including all stereochemical outcomes. If more than one major product is formed show both, including stereoisomers. If no reaction is expected then write (NR). 1) HOCH, 1)9-BN-H 2) NaOH. 1,0, CS Scanned with CamScanner
Question 19 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO4 2. H₂O₂ 18 17 16 CH3CO₂H (peroxyacid) 15 14 Pa or Pt (catalyst) 19 20 1 2 13 12 11 10 Pd or Ni (catalyst) D₂ (deuterium) (deuterium) A B H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br2 Br2 BH3⚫THF H₂O 0 D OCH3 а Br OCH3 Br OCH3 Br Br OCH3 Br OCH3 Br OCH3 de de de of Br OCH3 OCH3 'Br ABCD
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Question 9 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI ТСРВА 1. OsO4 2. H₂O₂ sl+H3 19 18 17 16 15 CH3CO₂H (peroxyacid) 14 MCPBA 13
13. Subject :- Chemistry
Question 15 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI Pd or Pt (catalyst) 20 1 2 19 18 17 16 15 14 13 12 11 10 MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br2 FIOH Pd or Ni (catalyst) D₂ (deuterium) A B с 000 ABCD ....O D
Question 17 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Bra CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI A 19 18 17 16 H2 Pd or Pt (catalyst) 20 1 2 HBr ROOR (peroxide) H₂O H₂SO4 HCI 6 1. BH₁.THF 2. H₂O2, NaOH 8 Br2 Br2 H₂O BH3⚫THF MCPBA 1. OsO4 2. H₂O₂ Неоно (peroxyacid) MCPBA 15 14 13 12 11 10 Pd or Ni (catalyst) (deuterium) B 0 D 44444 OH OH OH OH OH de de de de de OH 'OH OH OH Α ABCD
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Question 3 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. H₂ Pd or Pt (catalyst) 120 (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 20 1 2 18 17 16 15 14 13 HBr ROOR (peroxide) H₂O 12 11 10 MCPBA 1. OsO4 2. H₂O2 CH3CO₂H (peroxyacid) MCPBA A H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br₂ Pd or Ni (catalyst) D₂ (deuterium) EtOH B с D Br Br аа Br 'Br 8.8° Br Br 'Br 8.8° Α ABU C D Br 'Br