Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 17 2. (CH3)2S H2 Pd or Pt (catalyst) 20 1 2 HBr ROOR (peroxide) H₂O H₂SO4 HCI 6 1. BH₁.THF 8 2. H₂O₂, NaOH 12 11 10 9 Br2 Br2 CH₂OH 1. 03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) 19 18 17 16 15 MCPBA 14 13 A Br2 H₂O BH3⚫THF OH Pd or Ni (catalyst) (deuterium) B 0 D 44444 OH OH OH OH de de de de d OH 'OH OH OH OH OH Α ABCD
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 17 2. (CH3)2S H2 Pd or Pt (catalyst) 20 1 2 HBr ROOR (peroxide) H₂O H₂SO4 HCI 6 1. BH₁.THF 8 2. H₂O₂, NaOH 12 11 10 9 Br2 Br2 CH₂OH 1. 03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) 19 18 17 16 15 MCPBA 14 13 A Br2 H₂O BH3⚫THF OH Pd or Ni (catalyst) (deuterium) B 0 D 44444 OH OH OH OH de de de de d OH 'OH OH OH OH OH Α ABCD
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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