Question 13Please predict the products for each of the following reactions.Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).If a mixture of enantiomers is formed, please draw all the enantiomers.BrzCH3OH1.032. DMSKMnO4, NaOHcoldHI19181716151413Pd or Pt (catalyst)201MCPBA1. OsO42. H₂O₂CH3CO₂H(peroxyacid)MCPBA2. H₂O+HBrROOR (peroxide)H₂O912 11 10Pd or Ni (catalyst)D₂ (deuterium)FIOHH2SO4HCI1. BH3⚫THF2. H₂O2, NaOHBr2Br2H₂OBH3⚫THFABсDΑВABCDOH"OH४.४

In presence of peroxyacid , epoxidation to alkene occurs.

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 2. (CH3)2S zu 11 10 Pd or Pt (catalyst) 2 HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH, THF 2. H₂O2, NaOH Br2 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 20 18 17 16 15 14 1. OsO4 2. H₂O₂ 13 CH3CO₂H (peroxyacid) 12 A A B Br2 H₂O BH3⚫THF Br2 FIOH or Ni (catalyst) deuterium) B D OH OH OH "OH

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 2. (CH3)2S zu 11 10 Pd or Pt (catalyst) 2 HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH, THF 2. H₂O2, NaOH Br2 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 20 18 17 16 15 14 1. OsO4 2. H₂O₂ 13 CH3CO₂H (peroxyacid) 12 A A B Br2 H₂O BH3⚫THF Br2 FIOH or Ni (catalyst) deuterium) B D OH OH OH "OH

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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