Question 16 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 18 20 17 16 Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O H2SO4 HCI 12 11 10 9 8 1. BH3.THF 2. H₂O₂, NaOH Br₂ Br2 H₂O BH3⚫THF mCPBA 1. Os04 2. H₂O₂ HOD-HD (peroxyacid) MCPBA 15 14 13 A B ४.१ A ов C D D₂ (deuterium) D αα α.α

Question 16 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 18 20 17 16 Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O H2SO4 HCI 12 11 10 9 8 1. BH3.THF 2. H₂O₂, NaOH Br₂ Br2 H₂O BH3⚫THF mCPBA 1. Os04 2. H₂O₂ HOD-HD (peroxyacid) MCPBA 15 14 13 A B ४.१ A ов C D D₂ (deuterium) D αα α.α

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question 15 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI Pd or Pt (catalyst) 20 1 2 19 18 17 16 15 14 13 12 11 10 MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br2 FIOH Pd or Ni (catalyst) D₂ (deuterium) A B с 000 ABCD ....O D
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