Question 19 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or be If a mixture of enantiomers is formed, please draw all the enantiomers. CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Os04 2. H₂O₂ CHICO_H (peroxyacid) 18 17 16 15 14 13 19 2012 12 11 10 HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 H₂O BH3.THF Br₂ ° ABC D B Br Br OCH Br OCHS Br OCHS Br OCH OCH3 Br D ४.४

Chemistry
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Chapter1: Chemical Foundations
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Question 19
Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
Br₂
CH₂OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
18
19
20 1 2
17
16
HBr
ROOR (peroxide)
H₂O
H₂SO4
HCI
MCPBA
1. Os04
2. H₂O₂
(peroxyacid)
15
14
13
12 11 10
1. BH3.THF
2. H₂O2, NaOH
Br2
H₂O
BH3.THF
Br₂
B
D
OCH3
Br
Br
ď ď ď ď
Br
OCHS
OCH
Br
OCHS
Br
४.४
o de de de
Br
OCHS
OCH
ABC
о
D
Transcribed Image Text:Question 19 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br₂ CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 18 19 20 1 2 17 16 HBr ROOR (peroxide) H₂O H₂SO4 HCI MCPBA 1. Os04 2. H₂O₂ (peroxyacid) 15 14 13 12 11 10 1. BH3.THF 2. H₂O2, NaOH Br2 H₂O BH3.THF Br₂ B D OCH3 Br Br ď ď ď ď Br OCHS OCH Br OCHS Br ४.४ o de de de Br OCHS OCH ABC о D
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