Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. О А B A CH3OH Bra KMnO4, NaOH cold HI OH 1.03 2. DMS mCPBA OH 1. Os04 2. H₂O₂ 1. (CH3)25 18 17 16 15 19 14 CH3CO3H (peroxyacid) B 13 20 1. MCPBA - H30* 12 zu 8.8 ***OH 1 Pd or Pt (catalyst) Pd or Ni (catalyst) 2 11 10 D2 (deuterium) FIOH Br₂ BH 3 THF OH HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH3 THF 2. H₂O2, NaOH Br₂ Br₂ H₂O x OH "OH

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
О А
B
A
CH3OH
Bra
KMnO4, NaOH
cold
HI
OH
1.03
2. DMS
mCPBA
OH
1. Os04
2. H₂O₂
18
17
16
15
19
14
CH3CO3H
(peroxyacid)
B
13
1
20
12
1. MCPBA
· H30*
zu
8.8
Pd or Pt (catalyst)
***OH
2
Pd or Ni (catalyst)
D2 (deuterium)
FIOH
Br₂
11 10
BH 3 THF
OH
HBr
ROOR (peroxide)
H₂O
H₂SO4
HCI
1. BH3 THF
2. H₂O2, NaOH
Br₂
Br₂
H₂O
x
OH
"OH
Transcribed Image Text:Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. О А B A CH3OH Bra KMnO4, NaOH cold HI OH 1.03 2. DMS mCPBA OH 1. Os04 2. H₂O₂ 18 17 16 15 19 14 CH3CO3H (peroxyacid) B 13 1 20 12 1. MCPBA · H30* zu 8.8 Pd or Pt (catalyst) ***OH 2 Pd or Ni (catalyst) D2 (deuterium) FIOH Br₂ 11 10 BH 3 THF OH HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH3 THF 2. H₂O2, NaOH Br₂ Br₂ H₂O x OH "OH
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