tert-Cumyl chloride undergoes an Sŋ1 solvolysis reaction in aqueous acetone. CH3 CH3 H2O CI OH acetone Rank the derivatives of tert-cumyl chloride in order of increasing reactivity in this solvolysis. least reactive p-methoxy-tert-cumyl chloride m-nitro-tert-cumyl chloride p-fluoro-tert-cumyl chloride p-nitro-tert-cumyl chloride most reactive

tert-Cumyl chloride undergoes an Sŋ1 solvolysis reaction in aqueous acetone. CH3 CH3 H2O CI OH acetone Rank the derivatives of tert-cumyl chloride in order of increasing reactivity in this solvolysis. least reactive p-methoxy-tert-cumyl chloride m-nitro-tert-cumyl chloride p-fluoro-tert-cumyl chloride p-nitro-tert-cumyl chloride most reactive

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution

Section16.SE: Something Extra

Problem 47AP

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Question

tert-Cumyl chloride undergoes an Sy1 solvolysis reaction in aqueous acetone.
CH3
CH3
H2O
CI
OH
acetone
ČH3
CH3
Rank the derivatives of tert-cumyl chloride in order of increasing reactivity in this solvolysis.
least reactive
p-methoxy-tert-cumyl
chloride
m-nitro-tert-cumyl
chloride
p-fluoro-tert-cumyl
chloride
p-nitro-tert-cumyl
chloride
most reactive

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